Mathematical and physical modeling of the processes of reducing anthropogenic oxides during the combustion of water-saturated fuels

Detalhes bibliográficos
Parent link:Combustion and Flame.— .— Amsterdam: Elsevier Science Publishing Company Inc.
Vol. 274.— 2025.— Article number 113969, 16 p.
Outros Autores: Kuznetsov G. V. Geny Vladimirovich, Syrodoy S. V. Semen Vladimirovich, Kostoreva Zh. A. Zhanna Andreevna, Omarov A. A. Azimkhan Adilkhanovich, Gutareva N. Yu. Nadezhda Yurievna
Resumo:Title screen
The article presents the results of the experimental studies of heat and mass transfer processes occurring together under conditions of intense phase (evaporation of moisture) and thermochemical (interaction of fuel and oxidizer, formation of anthropogenic combustion products) transformations during the ignition and combustion of dry and wet coal particles. A mathematical model of the process of ignition of moisture-saturated coal particles has also been developed, which differs from the known ones by a detailed description of a complex of gas-phase and heterogeneous thermochemical reactions occurring both in the boundary layer of gases surrounding the fuel particle and in its porous structure. A comparative analysis of the theoretical and experimental values of ignition delay times and an analysis of the concentrations of anthropogenic gases (in particular, NO) has shown their good agreement. An important new element of the developed mathematical model is the description of the process of formation of nitric acid vapors during the induction period. The possibility of NOx sequestration under conditions of ignition of a wet coal fuel particle due to the binding of NOx during interaction with water vapor, the formation of nitric acid vapor and the subsequent intensive interaction of acid vapor with metal oxides formed during the thermal decomposition of coal during heating has been shown
Текстовый файл
AM_Agreement
Idioma:inglês
Publicado em: 2025
Assuntos:
Acesso em linha:https://doi.org/10.1016/j.combustflame.2025.113969
Formato: Recurso Electrónico Capítulo de Livro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=678613

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330 |a The article presents the results of the experimental studies of heat and mass transfer processes occurring together under conditions of intense phase (evaporation of moisture) and thermochemical (interaction of fuel and oxidizer, formation of anthropogenic combustion products) transformations during the ignition and combustion of dry and wet coal particles. A mathematical model of the process of ignition of moisture-saturated coal particles has also been developed, which differs from the known ones by a detailed description of a complex of gas-phase and heterogeneous thermochemical reactions occurring both in the boundary layer of gases surrounding the fuel particle and in its porous structure. A comparative analysis of the theoretical and experimental values of ignition delay times and an analysis of the concentrations of anthropogenic gases (in particular, NO) has shown their good agreement. An important new element of the developed mathematical model is the description of the process of formation of nitric acid vapors during the induction period. The possibility of NOx sequestration under conditions of ignition of a wet coal fuel particle due to the binding of NOx during interaction with water vapor, the formation of nitric acid vapor and the subsequent intensive interaction of acid vapor with metal oxides formed during the thermal decomposition of coal during heating has been shown 
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701 1 |a Kuznetsov  |b G. V.  |c Specialist in the field of heat power energy  |c Professor of Tomsk Polytechnic University, Doctor of Physical and Mathematical Sciences  |f 1949-  |g Geny Vladimirovich  |9 15963 
701 1 |a Syrodoy  |b S. V.  |c specialist in the field of thermal engineering  |c Professor of Tomsk Polytechnic University, Doctor of Technical Sciences  |f 1988-  |g Semen Vladimirovich  |9 18392 
701 1 |a Kostoreva  |b Zh. A.  |c Specialist in the field of heat and power engineering  |c Engineer of Tomsk Polytechnic University  |f 1994-  |g Zhanna Andreevna  |y Tomsk  |9 22104 
701 1 |a Omarov  |b A. A.  |g Azimkhan Adilkhanovich 
701 1 |a Gutareva  |b N. Yu.  |c linguist  |c Associate Professor of Tomsk Polytechnic University, Candidate of pedagogical sciences  |f 1979-  |g Nadezhda Yurievna  |9 15274 
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