Spectral and Cathodoluminescence Decay Characteristics of the Ba1−xCexF2+x (x = 0.3–0.4) Solid Solution Synthesized by Precipitation from Aqueous Solutions and Fusion

Dades bibliogràfiques
Parent link:Photonics.— .— Basel: MDPI AG
Vol. 10, iss. 9.— 2023.— Article number 1057, 14 p.
Autor corporatiu: National Research Tomsk Polytechnic University (570)
Altres autors: Kuznetsov S. V. Sergey Vladimirovich, Yasyrkina D. S. Darjya Semenovna, Valiev D. T. Damir Talgatovich, Stepanov S. A. Sergey Aleksandrovich, Aleksandrov A. A. Aleksandr Aleksandrovich, Batygov S. Kh. Sergey Khacheturovich, Voronov V. V. Valery Veniaminovich, Konyushkin V. A. Vasily Andreevich, Nakladov A. N. Andrey Nikolaevich, Ermakova Yu. A. Yuliya Aleksandrovna, Fedorov P. P. Pavel Pavlovich
Sumari:Title screen
Single-phase samples of the Ba1−xCexF2+x solid solution (x = 0.3–0.4) were synthesized by directional crystallization in the form of single crystals and by co-precipitation from aqueous nitrate solutions using potassium fluoride as a fluorinating agent in the form of nanopowders. The cathodoluminescence of the pressed powder samples was studied in comparison with the BaF2: Ce single crystals in 250–460 nm (2.7–5 eV) spectral range upon excitation by an electron accelerator. The cathodoluminescence spectra of the samples revealed a wide band in the range of 3.0–4.0 eV, which consists of two typical components of Ce3+ with decay time 23 ns in the case of single crystals and three decay times 27 ns, 140–170 ns, and ~600 ns in the case of pressed powders. The decay time of the short-wavelength component (27 ns) in the case of pressed powders is close to the lifetime of the excited state of the Ce3+ ion. The developed X-ray phosphors can be applied for embedding in diamonds for diamond–nanoparticle composite preparation
Текстовый файл
Idioma:anglès
Publicat: 2023
Matèries:
Accés en línia:http://earchive.tpu.ru/handle/11683/132505
https://doi.org/10.3390/photonics10091057
Format: Electrònic Capítol de llibre
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=675461

MARC

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330 |a Single-phase samples of the Ba1−xCexF2+x solid solution (x = 0.3–0.4) were synthesized by directional crystallization in the form of single crystals and by co-precipitation from aqueous nitrate solutions using potassium fluoride as a fluorinating agent in the form of nanopowders. The cathodoluminescence of the pressed powder samples was studied in comparison with the BaF2: Ce single crystals in 250–460 nm (2.7–5 eV) spectral range upon excitation by an electron accelerator. The cathodoluminescence spectra of the samples revealed a wide band in the range of 3.0–4.0 eV, which consists of two typical components of Ce3+ with decay time 23 ns in the case of single crystals and three decay times 27 ns, 140–170 ns, and ~600 ns in the case of pressed powders. The decay time of the short-wavelength component (27 ns) in the case of pressed powders is close to the lifetime of the excited state of the Ce3+ ion. The developed X-ray phosphors can be applied for embedding in diamonds for diamond–nanoparticle composite preparation 
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461 1 |t Photonics  |c Basel  |n MDPI AG 
463 1 |t Vol. 10, iss. 9  |v Article number 1057, 14 p.  |d 2023 
610 1 |a электронный ресурс 
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610 1 |a barium fluoride 
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701 1 |a Kuznetsov  |b S. V.  |g Sergey Vladimirovich 
701 1 |a Yasyrkina  |b D. S.  |g Darjya Semenovna 
701 1 |a Valiev  |b D. T.  |c specialist in the field of material science  |c Associate Professor of Tomsk Polytechnic University, Candidate of Physical and Mathematical Sciences  |f 1987-  |g Damir Talgatovich  |9 17370 
701 1 |a Stepanov  |b S. A.  |c specialist in the field of lightning engineering  |c Engineer of Tomsk Polytechnic University  |f 1986-  |g Sergey Aleksandrovich  |9 17369 
701 1 |a Aleksandrov  |b A. A.  |g Aleksandr Aleksandrovich 
701 1 |a Batygov  |b S. Kh.  |g Sergey Khacheturovich 
701 1 |a Voronov  |b V. V.  |g Valery Veniaminovich 
701 1 |a Konyushkin  |b V. A.  |g Vasily Andreevich 
701 1 |a Nakladov  |b A. N.  |g Andrey Nikolaevich 
701 1 |a Ermakova  |b Yu. A.  |g Yuliya Aleksandrovna 
701 1 |a Fedorov  |b P. P.  |g Pavel Pavlovich 
712 0 2 |a National Research Tomsk Polytechnic University  |c (2009- )  |9 27197  |4 570 
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