Composition, Combustion and Emission Characteristics of Distillation Fractions of Pyrolysis Oil of Waste Heavy-Duty Tires

Dettagli Bibliografici
Parent link:Waste and Biomass Valorization.— .— New York: Springer Nature
Vol. 15, iss. 6..— 2024.— P. 3841–3855
Ente Autore: National Research Tomsk Polytechnic University (570)
Altri autori: Kaltaev A. Albert, Slusarskiy (Slyusarsky) K. V. Konstantin Vitalievich, Gorshkov A. S. Alexander Sergeevich, Asilbekov A. Askar, Gubin A. V. Artur Vladimirovich, Larionov K. B. Kirill Borisovich
Riassunto:Title screen
The steam pyrolysis of end-of-life waste tires is viable technology for obtaining pyrolysis oil, which could be used as fuel. The purpose of current study is determining emission and combustion characteristics of different waste tires pyrolysis oil fractions as well as their chemical properties and composition. The pyrolysis oil was obtained by steam pyrolysis of waste heavy-duty vehicle tires at 500 °C, and distilled into 6 fractions with boiling temperatures varied in range of 60–448 °C. The higher boiling temperature fraction consisted of hydrocarbons with higher molecular weight. The maximal sulfur content was observed for 180–250 °C fraction. Ignition delay times of studied samples were varied in range of 0.58–5.38 s, flaming combustion times—2.16–4.28 s, total combustion times—2.73- 8.41 s. Both ignition delay and total combustion times had been monotonously increasing with boiling temperature of fraction, while flaming combustion times were increasing up to 300–350 °C fraction. Combustion behavior of all samples indicated significant contribution of homogeneous gas-phase reactions. Emission characteristics of pyrolysis oil and its individual fractions were majorly determined by their reactivity and composition. Higher CO, CO2 and NO emissions were observed for fractions with higher boiling temperatures, while SO2 emissions were independent of boiling temperature and were connected to sulfur content. Maximal sulfur oxide emissions were observed for fraction 180–250 °C. The NO emissions of initial pyrolysis oil sample were higher than for any of its fraction, while SO2—lower (with < 180 °C fraction as exception) indicating negative and positive synergistic effects, respectively.
Текстовый файл
AM_Agreement
Lingua:inglese
Pubblicazione: 2024
Soggetti:
Accesso online:https://doi.org/10.1007/s12649-024-02436-0
Natura: Elettronico Capitolo di libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=674376

MARC

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200 1 |a Composition, Combustion and Emission Characteristics of Distillation Fractions of Pyrolysis Oil of Waste Heavy-Duty Tires  |f A. Zh Kaltaev, K. V. Slyusarsky, A. S. Gorshkov [et al.] 
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330 |a The steam pyrolysis of end-of-life waste tires is viable technology for obtaining pyrolysis oil, which could be used as fuel. The purpose of current study is determining emission and combustion characteristics of different waste tires pyrolysis oil fractions as well as their chemical properties and composition. The pyrolysis oil was obtained by steam pyrolysis of waste heavy-duty vehicle tires at 500 °C, and distilled into 6 fractions with boiling temperatures varied in range of 60–448 °C. The higher boiling temperature fraction consisted of hydrocarbons with higher molecular weight. The maximal sulfur content was observed for 180–250 °C fraction. Ignition delay times of studied samples were varied in range of 0.58–5.38 s, flaming combustion times—2.16–4.28 s, total combustion times—2.73- 8.41 s. Both ignition delay and total combustion times had been monotonously increasing with boiling temperature of fraction, while flaming combustion times were increasing up to 300–350 °C fraction. Combustion behavior of all samples indicated significant contribution of homogeneous gas-phase reactions. Emission characteristics of pyrolysis oil and its individual fractions were majorly determined by their reactivity and composition. Higher CO, CO2 and NO emissions were observed for fractions with higher boiling temperatures, while SO2 emissions were independent of boiling temperature and were connected to sulfur content. Maximal sulfur oxide emissions were observed for fraction 180–250 °C. The NO emissions of initial pyrolysis oil sample were higher than for any of its fraction, while SO2—lower (with < 180 °C fraction as exception) indicating negative and positive synergistic effects, respectively. 
336 |a Текстовый файл 
371 0 |a AM_Agreement 
461 1 |t Waste and Biomass Valorization  |c New York  |n Springer Nature 
463 1 |t Vol. 15, iss. 6.  |v P. 3841–3855  |d 2024 
610 1 |a электронный ресурс 
610 1 |a труды учёных ТПУ 
610 1 |a Waste tires 
610 1 |a Steam pyrolysis 
610 1 |a Pyrolysis oil 
610 1 |a Distillation 
610 1 |a FTIR 
610 1 |a Ignition 
610 1 |a Combustion 
610 1 |a Emissions 
701 1 |a Kaltaev  |b A.  |c Physicist  |c Assistant of the Department of Tomsk Polytechnic University  |f 1995-  |g Albert  |9 22735 
701 1 |a Slusarskiy (Slyusarsky)  |b K. V.  |g Konstantin Vitalievich  |f 1990-  |c specialist in the field of power engineering  |c Associate Professor of Tomsk Polytechnic University, Candidate of Physical and Mathematical Sciences  |y Tomsk  |9 18803 
701 1 |a Gorshkov  |b A. S.  |c physicist  |c Associate Scientist of Tomsk Polytechnic University  |f 1999-  |g Alexander Sergeevich  |9 23063 
701 1 |a Asilbekov  |b A.  |c Specialist in the field of heat and power engineering  |c Engineer of Tomsk Polytechnic University  |f 1994-  |g Askar  |9 22956 
701 1 |a Gubin  |b A. V.  |c specialist in the field of electric power engineering  |c Engineer of Tomsk Polytechnic University  |f 2000-  |g Artur Vladimirovich  |9 23093 
701 1 |a Larionov  |b K. B.  |c specialist in the field of power engineering  |c Associate Professor of Tomsk Polytechnic University, Candidate of Technical Sciences  |f 1990-  |g Kirill Borisovich  |9 18865 
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