Generation of benzyne from aryl benziodoxaborole triflate under aqueous conditions and its reactions with alkyl aryl sulfides; Arkivoc; Vol. 1

Generation of benzyne from aryl benziodoxaborole triflate under aqueous conditions and its reactions with alkyl aryl sulfides; Arkivoc; Vol. 1

Opis bibliograficzny
Parent link:	Arkivoc.— .— New-York: ARKAT USA, Inc. Vol. 1.— 2024.— Article number 202412213, 11 p.
Korporacja:	National Research Tomsk Polytechnic University (570)
Kolejni autorzy:	Yoshimura A. Akira, Ngo Kim, Mironova I. A. Irina Andreevna, Gardner S. Zachary, Ogura Nami, Ueki Akiharu, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Saito Akio, Zhdankin V. V. Viktor Vladimirovich
Streszczenie:	Title screen Mesityl benziodoxaborole triflate is a unique benzyne precursor under aqueous conditions in the presence of NaHCO3 at room temperature. Reactions of alkyl aryl sulfides with benzyne generated under these conditions selectively afford the corresponding sulfonium salts. In contrast, the previously reported reactions of alkyl aryl sulfides with common benzyne precursors under strongly basic anhydrous conditions lead to various products of cyclization, rearrangement, or elimination but not to sulfonium salts. This very mild procedure can be further extended to the preparation of sulfonium salts from diaryl sulfides, dialkyl sulfides, cyclic alkyl and arylsulfides, as well as a selenonium salt from diphenyl selenide. Текстовый файл AM_Agreement
Język:	angielski
Wydane:	2024
Hasła przedmiotowe:	электронный ресурс труды учёных ТПУ hypervalent iodine benziodoxaborole benzyne iodonium salts sulfonium salts
Dostęp online:	https://doi.org/10.24820/ark.5550190.p012.213
Format:	Elektroniczne Rozdział
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=673457

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