Key-to-Lock Halogen Bond-Based Tetragonal Pyramidal Association of Iodonium Cations with the Lacune Rims of Beta-Octamolybdate; Chemical Science; Vol. 15, iss. 13

Key-to-Lock Halogen Bond-Based Tetragonal Pyramidal Association of Iodonium Cations with the Lacune Rims of Beta-Octamolybdate; Chemical Science; Vol. 15, iss. 13

Dades bibliogràfiques
Parent link:	Chemical Science.— .— London: Royal Society of Chemistry Vol. 15, iss. 13.— 2024.— P. 12459-12472
Autor corporatiu:	National Research Tomsk Polytechnic University (570)
Altres autors:	Soldatova N. S. Nataliya Sergeevna, Radzhabov A. D. Amirbek Dzhurabekovich, Ivanov D. M. Daniil Mikhaylovich, Burguera S. Sergi, Frontera A. Antonio, Abramov P. A. Pavel Aleksandrovich, Postnikov P. S. Pavel Sergeevich, Kukushkin V. Yu. Vadim Yurjevich
Sumari:	Title screen The structure-directing “key-to-lock” interaction of double σ-(IIII)-hole donating iodonium cations with the O-flanked pseudo-lacune rims of [β-Mo8O26]4– gives halogen-bonded iodonium–beta-octamolybate supramolecular associates. In the occurrence of their tetragonal pyramidal motifs, deep and broad σ-(IIII)-holes of a cation recognize the molybdate backbone, which provides an electronic pool localized around the two lacunae. The halogen-bonded I∙∙∙O linkages in the structures were thoroughly studied computationally and classified as two-center, three-center bifurcated, and unconventional “orthogonal” I∙∙∙O halogen bonds. In the latter, the O-atom approaches orthogonally the C–IIII–C plane of an iodonium cation and this geometry diverge from the IUPAC criteria for the identification of the halogen bond. Текстовый файл AM_Agreement
Idioma:	anglès
Publicat:	2024
Matèries:	электронный ресурс труды учёных ТПУ halogen bonding iodonium octamolybdate
Accés en línia:	https://doi.org/10.1039/D4SC01695E
Format:	Electrònic Capítol de llibre
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=673423

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