General Approach to Amides through Decarboxylative Radical Cross-Coupling of Carboxylic Acids and Isocyanides; Organic Letters; Vol. 26, iss. 16
| Parent link: | Organic Letters.— .— Washington: ACS Publications Vol. 26, iss. 16.— 2024.— P. 3380–3385 |
|---|---|
| Collectivité auteur: | |
| Autres auteurs: | , , , , , , , |
| Résumé: | Title screen Herein, we report a silver-catalyzed protocol for decarboxylative cross-coupling between carboxylic acids and isocyanides, leading to linear amide products through a free-radical mechanism. The disclosed approach provides a general entry to a variety of decorated amides, accommodating a diverse array of radical precursors, including aryl, heteroaryl, alkynyl, alkenyl, and alkyl carboxylic acids. Notably, the protocol proved to be efficient for decarboxylative late-stage functionalization of several elaborate pharmaceuticals, demonstrating its potential applications. Текстовый файл |
| Langue: | anglais |
| Publié: |
2024
|
| Sujets: | |
| Accès en ligne: | https://doi.org/10.1021/acs.orglett.4c00872 |
| Format: | Électronique Chapitre de livre |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=672791 |
MARC
| LEADER | 00000naa0a2200000 4500 | ||
|---|---|---|---|
| 001 | 672791 | ||
| 005 | 20240528143212.0 | ||
| 090 | |a 672791 | ||
| 100 | |a 20240528d2024 k||y0engy50 ba | ||
| 101 | 0 | |a eng | |
| 102 | |a US | ||
| 135 | |a drcn ---uucaa | ||
| 181 | 0 | |a i |b e | |
| 182 | 0 | |a b | |
| 183 | 0 | |a cr |2 RDAcarrier | |
| 200 | 1 | |a General Approach to Amides through Decarboxylative Radical Cross-Coupling of Carboxylic Acids and Isocyanides |f Qing Yan, Qing-Jia Yuan, A. Shatskiy [et al.] | |
| 203 | |a Текст |b визуальный |c электронный | ||
| 283 | |a online_resource |2 RDAcarrier | ||
| 300 | |a Title screen | ||
| 320 | |a References: 23 tit. | ||
| 330 | |a Herein, we report a silver-catalyzed protocol for decarboxylative cross-coupling between carboxylic acids and isocyanides, leading to linear amide products through a free-radical mechanism. The disclosed approach provides a general entry to a variety of decorated amides, accommodating a diverse array of radical precursors, including aryl, heteroaryl, alkynyl, alkenyl, and alkyl carboxylic acids. Notably, the protocol proved to be efficient for decarboxylative late-stage functionalization of several elaborate pharmaceuticals, demonstrating its potential applications. | ||
| 336 | |a Текстовый файл | ||
| 461 | 1 | |t Organic Letters |c Washington |n ACS Publications | |
| 463 | 1 | |t Vol. 26, iss. 16 |v P. 3380–3385 |d 2024 | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a электронный ресурс | |
| 701 | 0 | |a Qing Yan | |
| 701 | 0 | |a Qing-Jia Yuan | |
| 701 | 1 | |a Shatskiy |b A. |g Andrey | |
| 701 | 1 | |a Alvey |b G. R. |g Gregory | |
| 701 | 1 | |a Stepanova |b E. V. |c chemist |c Associate Professor of Tomsk Polytechnic University, Candidate of Chemical Sciences |f 1988- |g Elena Vladimirovna |9 17776 | |
| 701 | 0 | |a Jian-Quan Liu | |
| 701 | 1 | |a Karkas |b M. D. |g Markus | |
| 701 | 0 | |a Xiang-Shan Wang | |
| 712 | 0 | 2 | |a National Research Tomsk Polytechnic University |9 27197 |
| 801 | 0 | |a RU |b 63413507 |c 20240529 | |
| 856 | 4 | |u https://doi.org/10.1021/acs.orglett.4c00872 |z https://doi.org/10.1021/acs.orglett.4c00872 | |
| 942 | |c CR | ||