Metal-free and Atom-efficient Protocol for Diarylation of Selenocyanate by Diaryliodonium Salts

Metal-free and Atom-efficient Protocol for Diarylation of Selenocyanate by Diaryliodonium Salts

Bibliographic Details
Parent link:Organic and Biomolecular Chemistry.— .— London: Royal Society of Chemistry
Vol. 21 - iss. 33.— 2023.— P. 6743-6749
Corporate Author: National Research Tomsk Polytechnic University
Other Authors: Radzhabov A. D. Amirbek Dzhurabekovich, Soldatova N. S. Nataliya Sergeevna, Ivanov D. M. Daniil Mikhaylovich, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Kukushkin V. Yu. Vadim Yurjevich, Postnikov P. S. Pavel Sergeevich
Summary:The rational search for the efficient protocols for atom-efficient arylation utilizing iodonium salts is the genuine need for the sustainability and green chemistry. We developed a novel approach toward metal-free diarylation of selenocyanate using trimethoxyphenyl-substituted iodonium salts with the formation of appropriate diarylselenides. The suggested procedure allows the preparation of a series of diarylselenides without isolation and purification of intermediate products in two-step one-pot sequence.
Текстовый файл
Language:English
Published: 2023
Subjects:
diaryliodonium salts
diarylation
atom-efficiency
selenocyanate
metal-free substitution
труды учёных ТПУ
электронный ресурс
Online Access:https://doi.org/10.1039/d3ob00833a
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=672720

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