Preparation and X‑ray Structural Study of Dibenzobromolium and Dibenzochlorolium Derivatives; ACS Omega; Vol. 9 - iss. 2

Preparation and X‑ray Structural Study of Dibenzobromolium and Dibenzochlorolium Derivatives; ACS Omega; Vol. 9 - iss. 2

Bibliografische gegevens
Parent link:	ACS Omega.— .— Washington: American Chemical Society Vol. 9 - iss. 2.— 2024.— P. 2664-2673
Coauteur:	Томский политехнический университет
Andere auteurs:	Huss C. Christopher, Yoshimura A. Akira, Rohde G. Gregory, Mironova I. A. Irina Andreevna, Postnikov P. S. Pavel Sergeevich, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Saito A. Akio, Zhdankin V. Viktor
Samenvatting:	Various five-membered cyclic dibenzobromolium salts (dibenzo[b,d]bromol-5-ium chloride, nitrate, hydrogen sulfate, dihydrogen phosphate, trifluoroacetate, and tetrafluoroborate) were prepared by diazotization−cyclization of 2′-bromo-[1,1′-biphenyl]-2-amine in solution of appropriate acids. The chlorolium analogues (iodide, trifluoroacetate, and tetrafluoroborate) were obtained by a similar procedure. Additional dibenzohalolium derivatives (dibenzo[b,d]bromol-5-ium and dibenzo[b,d]chlorol-5-ium azides, bis(trifluoromethanesulfonyl)imidates, thiocyanates, and trifluoromethanesulfonates) were prepared by anion exchange. Structures of ten of these dibenzohalolium derivatives were established by X-ray analysis. Bond distances and angles for the halogen atoms in different dibenzohalolium derivatives were summarized and discussed. Текстовый файл
Taal:	Engels
Gepubliceerd in:	2024
Onderwerpen:	anions chemical reactions chemical structure crystal structure salts труды учёных ТПУ электронный ресурс
Online toegang:	https://doi.org/10.1021/acsomega.3c07512
Formaat:	Elektronisch Hoofdstuk
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=672655

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