Laser-Induced photothermal activation of multilayer MoS2 with spatially controlled catalytic activity
| Parent link: | Journal of Colloid and Interface Science.— .— Amsterdam: Elsevier Science Publishing Company Inc. Vol. 654, Pt. A.— 2024.— P. 114-123 |
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| Autor Corporativo: | |
| Otros Autores: | , , , , , , , , |
| Sumario: | Title screen This study investigates the effects of high-power laser irradiation on multilayer MoS2, a promising material for catalysis, optoelectronics, and energy applications. In addition to previously reported sculpting of MoS2 layers, we discovered a novel effect of laser-induced photothermal heating that drives the chemical activation of MoS2. The photothermal effect was confirmed by temperature-dependent experiments, in situ temperature measurements with nanolocalized probes, and simulations. Remarkably, we observed the reduction of Ag+ ions on laser-irradiated MoS2 layers, forming plasmonic nanostructures without external stimuli such as photons or chemical reducing agents. We attribute this phenomenon to the significant defect density within the laser-carved region and the surrounding area induced by photothermal effects. Further functionalization of the laser-modified MoS2 with 4-nitrobenzenethiol self-assembled monolayers demonstrated a significant increase in photocatalytic activity, close to 100% yield compared to the negligible activity of pristine material. Our findings contribute to a deeper understanding of the light-induced modification of MoS2 properties and introduce a novel method for spatially controlling the chemical activation of MoS2. This advancement holds significant potential in developing high-performance 2D semiconductors as nano-engineered catalytic materials Текстовый файл |
| Publicado: |
2024
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| Materias: | |
| Acceso en línea: | https://doi.org/10.1016/j.jcis.2023.10.027 |
| Formato: | Electrónico Capítulo de libro |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=672623 |
| Sumario: | Title screen This study investigates the effects of high-power laser irradiation on multilayer MoS2, a promising material for catalysis, optoelectronics, and energy applications. In addition to previously reported sculpting of MoS2 layers, we discovered a novel effect of laser-induced photothermal heating that drives the chemical activation of MoS2. The photothermal effect was confirmed by temperature-dependent experiments, in situ temperature measurements with nanolocalized probes, and simulations. Remarkably, we observed the reduction of Ag+ ions on laser-irradiated MoS2 layers, forming plasmonic nanostructures without external stimuli such as photons or chemical reducing agents. We attribute this phenomenon to the significant defect density within the laser-carved region and the surrounding area induced by photothermal effects. Further functionalization of the laser-modified MoS2 with 4-nitrobenzenethiol self-assembled monolayers demonstrated a significant increase in photocatalytic activity, close to 100% yield compared to the negligible activity of pristine material. Our findings contribute to a deeper understanding of the light-induced modification of MoS2 properties and introduce a novel method for spatially controlling the chemical activation of MoS2. This advancement holds significant potential in developing high-performance 2D semiconductors as nano-engineered catalytic materials Текстовый файл |
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| DOI: | 10.1016/j.jcis.2023.10.027 |