Investigation of the Interaction of Palladium with Potassium Tetrafluorobromate; Journal of Physics: Conference Series; Vol. 1443 : Issues of Physics and Technology in Science, Power Industry and Medicine" (IPTSPIM-2019)
| Parent link: | Journal of Physics: Conference Series.— .— Bristol: IOP Publishing Ltd. Vol. 1443 : Issues of Physics and Technology in Science, Power Industry and Medicine" (IPTSPIM-2019).— 2020.— Article number 012021, 7 p. |
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| Autor corporatiu: | |
| Altres autors: | , , , , |
| Sumari: | Title screen In this investigation, the interaction of metallic palladium with potassium tetrafluorobromate was examined in open system, the reaction products were identified using X-ray phase analysis. A thermogram of the interaction of Pd with KBrF4 was obtained, the temperature range of the reaction (187.9-328°C) and the thermal effect (431.31 J/g) were determined. It was found that the fluorination process is a multi-stage process. The solubility of the obtained K2PdF6 compound in nitric and hydrochloric acids was investigated. The process of extraction of palladium from nitric acid solutions with tributyl phosphate was carried out and the influence of the concentration of palladium and the acidity of the initial solution on the distribution coefficient was investigated Текстовый файл |
| Idioma: | anglès |
| Publicat: |
2020
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| Matèries: | |
| Accés en línia: | https://doi.org/10.1088/1742-6596/1443/1/012021 |
| Format: | Electrònic Capítol de llibre |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=672591 |
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| 200 | 1 | |a Investigation of the Interaction of Palladium with Potassium Tetrafluorobromate |f A. Mamatova, A. M. Shakimova, K. I. Merkel [et al.] | |
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| 330 | |a In this investigation, the interaction of metallic palladium with potassium tetrafluorobromate was examined in open system, the reaction products were identified using X-ray phase analysis. A thermogram of the interaction of Pd with KBrF4 was obtained, the temperature range of the reaction (187.9-328°C) and the thermal effect (431.31 J/g) were determined. It was found that the fluorination process is a multi-stage process. The solubility of the obtained K2PdF6 compound in nitric and hydrochloric acids was investigated. The process of extraction of palladium from nitric acid solutions with tributyl phosphate was carried out and the influence of the concentration of palladium and the acidity of the initial solution on the distribution coefficient was investigated | ||
| 336 | |a Текстовый файл | ||
| 461 | 1 | |t Journal of Physics: Conference Series |c Bristol |n IOP Publishing Ltd. | |
| 463 | 1 | |t Vol. 1443 : Issues of Physics and Technology in Science, Power Industry and Medicine" (IPTSPIM-2019) |o International Conference for Young Scientists, 30 September-5 October 2019, Tomsk, Russia |v Article number 012021, 7 p. |d 2020 | |
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a metallic palladium | |
| 610 | 1 | |a potassium | |
| 610 | 1 | |a thermogram of the interaction | |
| 701 | 1 | |a Mamatova |b A. M. |g Alina Manasovna |f 1998- |c Chemical Engineer |c Engineer of Tomsk Polytechnic University |9 88547 | |
| 701 | 1 | |a Shakimova |b A. M. | |
| 701 | 1 | |a Merkel |b K. I. | |
| 701 | 1 | |a Malin |b A. V. |c chemical engineer |c engineer of Tomsk Polytechnic University |f 1992- |g Artem Vladimirovich |9 21553 | |
| 701 | 1 | |a Ostvald |b R. V. |c Chemical Engineer |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences |f 1980- |g Roman Vyacheslavovich |9 15416 | |
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