Study of the high-energy alpha particles influence on the styrene accumulation kinetics and functional groups during the synthesis of proton-exchange membranes based on PVDF
| Parent link: | Radiation Physics and Chemistry.— .— Amsterdam: Elsevier Science Publishing Company Inc. Vol. 221.— 2024.— Article number 111745, 9 p. |
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| Other Authors: | , , , |
| Summary: | Title screen The study investigates the effect of alpha irradiation on the graft copolymerization of styrene with polyvinylidene fluoride (PVDF). Using methods of radiation-chemical modification, a proton exchange membrane (PEM) with a uniform distribution of functional sulfate groups throughout the entire volume was developed. Grafting of styrene was carried out at different temperatures and solution concentrations. Functional sulfo-groups were added to the graft polymer by sulfonation, with the addition of solvents. The degree of grafting (DG), water absorption (W) and exchange capacity (IEC) correlate well with the absorbed dose and alpha particle fluence. Research into this method will allow us to develop an affordable industrial technology for widespread implementation Текстовый файл AM_Agreement |
| Published: |
2024
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| Subjects: | |
| Online Access: | https://doi.org/10.1016/j.radphyschem.2024.111745 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=672467 |
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| 200 | 1 | |a Study of the high-energy alpha particles influence on the styrene accumulation kinetics and functional groups during the synthesis of proton-exchange membranes based on PVDF |f V. V. Sokhoreva, М. Koptsev, I. V. Lomov, D. B. Mukhambetalin | |
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| 330 | |a The study investigates the effect of alpha irradiation on the graft copolymerization of styrene with polyvinylidene fluoride (PVDF). Using methods of radiation-chemical modification, a proton exchange membrane (PEM) with a uniform distribution of functional sulfate groups throughout the entire volume was developed. Grafting of styrene was carried out at different temperatures and solution concentrations. Functional sulfo-groups were added to the graft polymer by sulfonation, with the addition of solvents. The degree of grafting (DG), water absorption (W) and exchange capacity (IEC) correlate well with the absorbed dose and alpha particle fluence. Research into this method will allow us to develop an affordable industrial technology for widespread implementation | ||
| 336 | |a Текстовый файл | ||
| 371 | 0 | |a AM_Agreement | |
| 461 | 1 | |t Radiation Physics and Chemistry |c Amsterdam |n Elsevier Science Publishing Company Inc. | |
| 463 | 1 | |t Vol. 221 |v Article number 111745, 9 p. |d 2024 | |
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a fuel cell | |
| 610 | 1 | |a radiation-modified proton-exchange membrane | |
| 610 | 1 | |a irradiation | |
| 610 | 1 | |a alpha particles | |
| 610 | 1 | |a proton conductivity | |
| 701 | 1 | |a Sokhoreva |b V. V. |c physicist |c Senior researcher of Tomsk Polytechnic University |f 1944- |g Valentina Viktorovna |9 15409 | |
| 701 | 1 | |a Koptsev |b M. |c physicist |c Engineer of Tomsk Polytechnic University |f 1994- |g Maksim |9 23020 | |
| 701 | 1 | |a Lomov |b I. V. |c specialist in the field of power engineering |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences |f 1981- |g Ivan Viktorovich |9 16827 | |
| 701 | 1 | |a Mukhambetalin |b D. B. |c physicist |c Senior Lecturer of Tomsk Polytechnic University |f 1996- |g Danyshpan Bolatuly |y Tomsk |9 88540 | |
| 712 | 0 | 2 | |a National Research Tomsk Polytechnic University |c (2009- ) |9 27197 |
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