Identification of photolysis products of aqueous sodium thiosulfate solutions; High Energy Chemistry; Vol. 57, No. 3

Bibliografiske detaljer
Parent link:High Energy Chemistry.— .— New York: Springer Science+Business Media LLC.
Vol. 57, No. 3.— 2023.— P. 397-401
Institution som forfatter: Томский политехнический университет
Andre forfattere: Egorov N. B. Nikolai Borisovich, Isaeva E. A. Evgeniya Andreevna, Dmitrieva A. A. Anna Aleksandrovna, Kulikova A. V. Arina Vyacheslavovna, Voroshilov F. A. Fedor Anatolievich, Zherin (Gerin) I. I. Ivan Ignatyevich
Summary:Title screen
The results of identification of photolysis products of air-saturated aqueous solutions of Na2S2O3 irradiated with a KrCl excimer lamp are presented. Using spectrophotometry, HPLC, IR spectroscopy, and mass spectrometry, it has been shown that intermediate photolysis products are colloidal sulfur and tetrathionate and pentathionate ions, which photodegrade to form sulfur, sulfate ions, and hydrogen sulfide during further UV irradiation involving atmospheric oxygen and solvent molecules. Reactions for the formation of detected photolysis products have been proposed
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AM_Agreement
Sprog:engelsk
Udgivet: 2023
Fag:
Online adgang:https://doi.org/10.1134/S0018143923090047
Format: Electronisk Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=672451

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