A novel impedimetric sensor based on N-acetyl-L-cysteine for the determination of hydroxyl radicals in cell cultures in vitro; Talanta; Vol. 270

Bibliografiske detaljer
Parent link:Talanta.— .— Amsterdam: Elsevier Science Publishing Company Inc.
Vol. 270.— 2024.— Article number 125600, 8 p.
Andre forfattere: Erkovich A. V. Alina Vadimovna, Korotkova E. I. Elena Ivanovna, Dorozhko E. V. Elena Vladimirovna, Plotnikov E. V. Evgeny Vladimirovich, Semin V. O. Viktor Olegovich, Chernova A. P. Anna Pavlovna, Barek J. Jiri, Solomonenko A. N. Anna Nikolaevna, Aseeva N. V. Natalya Valerevna
Summary:Title screen
We report a novel impedimetric sensor based on a graphite electrode impregnated with polyethylene and paraffin under vacuum (IGE) modified with electrochemically deposited gold and a self-assembled monolayer of N-acetyl-L-cysteine (NAC/Au/IGE) for selective and sensitive determination of extracellular hydroxyl radicals (OH•) generated by living cells. The application of a sulphur-containing molecule oxidized by OH• predicts the high selectivity of the sensor, and the utilization of the non-faradaic impedance spectroscopy for recording an analytical response makes it possible to achieve superior sensitivity with a detection limit of 0.01 nM and a linear dynamic range of 0.08–8 nM. Meanwhile, NAC/Au/IGE demonstrated a strong potential of detecting OH• generated by biological objects via successful determination of extracellular hydroxyl radicals generated by normal fibroblast cells and prostate carcinoma cells
Текстовый файл
AM_Agreement
Sprog:engelsk
Udgivet: 2024
Fag:
Online adgang:https://doi.org/10.1016/j.talanta.2023.125600
Format: xMaterials Electronisk Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=672390

MARC

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200 1 |a A novel impedimetric sensor based on N-acetyl-L-cysteine for the determination of hydroxyl radicals in cell cultures in vitro  |f A. V. Erkovich, E. I. Korotkova, E. V. Dorozhko [et al.] 
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330 |a We report a novel impedimetric sensor based on a graphite electrode impregnated with polyethylene and paraffin under vacuum (IGE) modified with electrochemically deposited gold and a self-assembled monolayer of N-acetyl-L-cysteine (NAC/Au/IGE) for selective and sensitive determination of extracellular hydroxyl radicals (OH•) generated by living cells. The application of a sulphur-containing molecule oxidized by OH• predicts the high selectivity of the sensor, and the utilization of the non-faradaic impedance spectroscopy for recording an analytical response makes it possible to achieve superior sensitivity with a detection limit of 0.01 nM and a linear dynamic range of 0.08–8 nM. Meanwhile, NAC/Au/IGE demonstrated a strong potential of detecting OH• generated by biological objects via successful determination of extracellular hydroxyl radicals generated by normal fibroblast cells and prostate carcinoma cells 
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610 1 |a электронный ресурс 
610 1 |a труды учёных ТПУ 
610 1 |a hydroxyl radical 
610 1 |a impedimetric sensor 
610 1 |a cell cultures 
610 1 |a N-Acetyl-L-cysteine 
610 1 |a oxidative stress 
701 1 |a Erkovich  |b A. V.  |c chemical technologist  |c engineer of Tomsk Polytechnic University  |f 1997-  |g Alina Vadimovna  |9 23015 
701 1 |a Korotkova  |b E. I.  |c chemist  |c Professor of Tomsk Polytechnic University, Doctor of chemical science  |f 1965-  |g Elena Ivanovna  |9 15456 
701 1 |a Dorozhko  |b E. V.  |c chemist  |c Engineer of Tomsk Polytechnic University  |f 1979-  |g Elena Vladimirovna  |9 16175 
701 1 |a Plotnikov  |b E. V.  |c chemist  |c Associate Professor of Tomsk Polytechnic University, Candidate of Chemical Sciences  |f 1983-  |g Evgeny Vladimirovich  |9 16417 
701 1 |a Semin  |b V. O.  |g Viktor Olegovich 
701 1 |a Chernova  |b A. P.  |c chemist  |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences  |f 1984-  |g Anna Pavlovna  |9 22278 
701 1 |a Barek  |b J.  |c Czech chemist  |c Professor of Tomsk Polytechnic University, candidate of chemical Sciences  |f 1949-  |g Jiri  |9 21069 
701 1 |a Solomonenko  |b A. N.  |c Chemical engineer  |c Engineer of Tomsk Polytechnic University  |f 1995-  |g Anna Nikolaevna  |9 22606 
701 1 |a Aseeva  |b N. V.  |c Chemical engineer  |c Engineer of Tomsk Polytechnic University  |f 1995-  |g Natalya Valerevna  |9 22125 
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