Studying the alkylbenzenes sulfonation process using the mathematical model considering the mass transfer

מידע ביבליוגרפי
Parent link:South African Journal of Chemical Engineering.— .— Amsterdam: Elsevier Science Publishing Company Inc.
Vol. 48.— 2024.— P. 196-203
מחבר תאגידי: National Research Tomsk Polytechnic University
מחברים אחרים: Dolganova I. O. Irena Olegovna, Dolganov I. M. Igor Mikhailovich, Ivashkina E. N. Elena Nikolaevna, Zykova А. А. Anastasiya Aleksandrovna, Sladkov D. Yu. Denis Yurjevich
סיכום:Title screen
Linear alkylbenzene sulfonic acid (ABSA) is used to produce industrial and domestic synthetic detergents and is obtained via a multistage technology. Unsteady-state mathematical model considering mass transfer was developed for linear alkylbenzenes (LAB) sulfonation technological stage. With use of the developed model we studied how the modes in the film sulfonation reactor influence the product quality and yield. The varied parameters were SO3 concentration in the air flow, process temperature and SO3/LAB molar ratio. It was found that the air flow rate of 10,000 m3/h, temperature 30 °C, pressure 170 kPa are the optimal process conditions. Under these conditions, the degree of the feedstock conversion is close to 1, and the share of the target product is about 98.4 wt.%
AM_Agreement
שפה:אנגלית
יצא לאור: 2024
נושאים:
גישה מקוונת:https://doi.org/10.1016/j.sajce.2024.01.011
פורמט: אלקטרוני Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=672210

MARC

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330 |a Linear alkylbenzene sulfonic acid (ABSA) is used to produce industrial and domestic synthetic detergents and is obtained via a multistage technology. Unsteady-state mathematical model considering mass transfer was developed for linear alkylbenzenes (LAB) sulfonation technological stage. With use of the developed model we studied how the modes in the film sulfonation reactor influence the product quality and yield. The varied parameters were SO3 concentration in the air flow, process temperature and SO3/LAB molar ratio. It was found that the air flow rate of 10,000 m3/h, temperature 30 °C, pressure 170 kPa are the optimal process conditions. Under these conditions, the degree of the feedstock conversion is close to 1, and the share of the target product is about 98.4 wt.% 
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461 1 |t South African Journal of Chemical Engineering  |c Amsterdam  |n Elsevier Science Publishing Company Inc. 
463 1 |t Vol. 48  |v P. 196-203  |d 2024 
610 1 |a электронный ресурс 
610 1 |a труды учёных ТПУ 
610 1 |a sulfonation 
610 1 |a alkylbenzene 
610 1 |a alkylbenzenesulfonic acid 
610 1 |a sulfuric anhydride 
610 1 |a mathematical model 
610 1 |a mass transfer 
701 1 |a Dolganova  |b I. O.  |c chemist  |c Associate Scientist of Tomsk Polytechnic University, postgraduate student, candidate of technical Sciences  |f 1988-  |g Irena Olegovna  |9 15449 
701 1 |a Dolganov  |b I. M.  |c Chemical Engineer  |c Associate Professor of Tomsk Polytechnic University, Candidate of Technical Sciences  |f 1987-  |g Igor Mikhailovich  |9 16216 
701 1 |a Ivashkina  |b E. N.  |c Chemical Engineer  |c Professor of Tomsk Polytechnic University, Doctor of technical sciences  |f 1983-  |g Elena Nikolaevna  |y Tomsk  |9 15453 
701 1 |a Zykova  |b А. А.  |c chemical engineer  |c Engineer of Tomsk Polytechnic University, Candidate of technical sciences  |f 1994-  |g Anastasiya Aleksandrovna  |y Tomsk  |9 88529 
701 1 |a Sladkov  |b D. Yu.  |c chemical engineer  |c Engineer of Tomsk Polytechnic University  |f 1999-  |g Denis Yurjevich  |y Tomsk  |9 88527 
712 0 2 |a National Research Tomsk Polytechnic University  |c (2009- )  |9 27197 
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