Analysis of the Ro-Vibrational Structure of the Fundamental Band ν6 of 13CHF3 Molecule

Manylion Llyfryddiaeth
Parent link:Optics and Spectroscopy
Vol. 130, iss. 2.— 2022.— [P. 35-41]
Awdur Corfforaethol: Национальный исследовательский Томский политехнический университет Исследовательская школа физики высокоэнергетических процессов
Awduron Eraill: Bekhtereva E. S. Elena Sergeevna, Fomchenko A. L. Anna Leonidovna, Ersin T. Tolganay, Bauerecker S. Sigurd
Crynodeb:Title screen
The high-resolution IR spectrum of the fundamental band ν6 of 13CHF3 molecule, located in the region of 450-750 cm-1, has been investigated. The spectrum was analyzed based on the ground-state combination-difference method. About 5500 transitions were assigned as a result of the analysis, based on which 2607 experimental values of ro-vibrational energies in the state ν6 = 1 were determined. The results surpass the data known in the literature, both in the amount of obtained experimental data and in the number of highly excited ro-vibrational energy levels extracted from these data. Based on the information extracted from the spectrum, the spectroscopic parameters of the state under consideration were determined, which reproduce the initial data with an error of 4.4 × 10-5 cm-1.
Режим доступа: по договору с организацией-держателем ресурса
Cyhoeddwyd: 2022
Pynciau:
Mynediad Ar-lein:https://doi.org/10.1134/S0030400X22010039
Fformat: Electronig Pennod Llyfr
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=669434
Disgrifiad
Crynodeb:Title screen
The high-resolution IR spectrum of the fundamental band ν6 of 13CHF3 molecule, located in the region of 450-750 cm-1, has been investigated. The spectrum was analyzed based on the ground-state combination-difference method. About 5500 transitions were assigned as a result of the analysis, based on which 2607 experimental values of ro-vibrational energies in the state ν6 = 1 were determined. The results surpass the data known in the literature, both in the amount of obtained experimental data and in the number of highly excited ro-vibrational energy levels extracted from these data. Based on the information extracted from the spectrum, the spectroscopic parameters of the state under consideration were determined, which reproduce the initial data with an error of 4.4 × 10-5 cm-1.
Режим доступа: по договору с организацией-держателем ресурса
DOI:10.1134/S0030400X22010039