Analysis of the Ro-Vibrational Structure of the Fundamental Band ν6 of 13CHF3 Molecule; Optics and Spectroscopy; Vol. 130, iss. 2

書誌詳細
Parent link:Optics and Spectroscopy
Vol. 130, iss. 2.— 2022.— [P. 35-41]
団体著者: Национальный исследовательский Томский политехнический университет Исследовательская школа физики высокоэнергетических процессов
その他の著者: Bekhtereva E. S. Elena Sergeevna, Fomchenko A. L. Anna Leonidovna, Ersin T. Tolganay, Bauerecker S. Sigurd
要約:Title screen
The high-resolution IR spectrum of the fundamental band ν6 of 13CHF3 molecule, located in the region of 450-750 cm-1, has been investigated. The spectrum was analyzed based on the ground-state combination-difference method. About 5500 transitions were assigned as a result of the analysis, based on which 2607 experimental values of ro-vibrational energies in the state ν6 = 1 were determined. The results surpass the data known in the literature, both in the amount of obtained experimental data and in the number of highly excited ro-vibrational energy levels extracted from these data. Based on the information extracted from the spectrum, the spectroscopic parameters of the state under consideration were determined, which reproduce the initial data with an error of 4.4 × 10-5 cm-1.
Режим доступа: по договору с организацией-держателем ресурса
言語:英語
出版事項: 2022
主題:
オンライン・アクセス:https://doi.org/10.1134/S0030400X22010039
フォーマット: 電子媒体 図書の章
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=669434
その他の書誌記述
要約:Title screen
The high-resolution IR spectrum of the fundamental band ν6 of 13CHF3 molecule, located in the region of 450-750 cm-1, has been investigated. The spectrum was analyzed based on the ground-state combination-difference method. About 5500 transitions were assigned as a result of the analysis, based on which 2607 experimental values of ro-vibrational energies in the state ν6 = 1 were determined. The results surpass the data known in the literature, both in the amount of obtained experimental data and in the number of highly excited ro-vibrational energy levels extracted from these data. Based on the information extracted from the spectrum, the spectroscopic parameters of the state under consideration were determined, which reproduce the initial data with an error of 4.4 × 10-5 cm-1.
Режим доступа: по договору с организацией-держателем ресурса
DOI:10.1134/S0030400X22010039