Comparative analysis of working gas composition impact on diamond films microstructure; Surfaces and Interfaces; Vol. 37

Dettagli Bibliografici
Parent link:Surfaces and Interfaces
Vol. 37.— 2023.— [102717, 7 p.]
Ente Autore: Национальный исследовательский Томский политехнический университет Инженерная школа новых производственных технологий Научно-производственная лаборатория "Импульсно-пучковых, электроразрядных и плазменных технологий"
Altri autori: Gaydaychuk A. V. Alexander Valerievich, Linnik S. A. Stepan Andreevich, Mitulinsky A. S. Aleksandr Sergeevich, Zenkin S. P. Sergey Petrovich, Bulakh V. A. Vlada Aleksandrovna
Riassunto:Title screen
The paper report a diamond films with dendrite-like or nanofeathers structure. Such structures was synthesized both in CH4/H2 (12.2–19.3 vol.% CH4) and CH4/H2/N2 (7–18.5 vol.% N2) working gas mixture. The resulting diamond dendrites are composed of diamond crystallites of various sizes, as well as non-diamond carbon, with a height comparable to the film thickness and a lateral size does not exceed 200 nm (the minimum size of detected diamond crystallites is ? 5 nm). Such diamond structure seems cannot be classified to either conventionally nano- or ultrananocrystalline films. It is shown that nitrogen-rich diamond films have a larger size of both individual diamond crystallites and dendrites, as well as a higher level of residual stresses and roughness, compared to nitrogen-free diamond films. At the same time, nitrogen-free films have higher values of hardness and Young's modulus.
Режим доступа: по договору с организацией-держателем ресурса
Lingua:inglese
Pubblicazione: 2023
Soggetti:
Accesso online:https://doi.org/10.1016/j.surfin.2023.102717
Natura: MixedMaterials Elettronico Capitolo di libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=669383

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300 |a Title screen 
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330 |a The paper report a diamond films with dendrite-like or nanofeathers structure. Such structures was synthesized both in CH4/H2 (12.2–19.3 vol.% CH4) and CH4/H2/N2 (7–18.5 vol.% N2) working gas mixture. The resulting diamond dendrites are composed of diamond crystallites of various sizes, as well as non-diamond carbon, with a height comparable to the film thickness and a lateral size does not exceed 200 nm (the minimum size of detected diamond crystallites is ? 5 nm). Such diamond structure seems cannot be classified to either conventionally nano- or ultrananocrystalline films. It is shown that nitrogen-rich diamond films have a larger size of both individual diamond crystallites and dendrites, as well as a higher level of residual stresses and roughness, compared to nitrogen-free diamond films. At the same time, nitrogen-free films have higher values of hardness and Young's modulus. 
333 |a Режим доступа: по договору с организацией-держателем ресурса 
461 |t Surfaces and Interfaces 
463 |t Vol. 37  |v [102717, 7 p.]  |d 2023 
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701 1 |a Gaydaychuk  |b A. V.  |c physicist  |c Postgraduate, Engineer - Researcher of Tomsk Polytechnic University  |f 1984-  |g Alexander Valerievich  |3 (RuTPU)RU\TPU\pers\32876  |9 16724 
701 1 |a Linnik  |b S. A.  |c physicist  |c Engineer-Researcher of Tomsk Polytechnic University  |f 1985-  |g Stepan Andreevich  |3 (RuTPU)RU\TPU\pers\32877  |9 16725 
701 1 |a Mitulinsky  |b A. S.  |c electric power specialist  |c technician of Tomsk Polytechnic University  |f 1998-  |g Aleksandr Sergeevich  |3 (RuTPU)RU\TPU\pers\47113 
701 1 |a Zenkin  |b S. P.  |c physicist  |c Researcher of Tomsk Polytechnic University  |f 1988-  |g Sergey Petrovich  |3 (RuTPU)RU\TPU\pers\41880 
701 1 |a Bulakh  |b V. A.  |c chemist  |c Technician of Tomsk Polytechnic University  |f 2002-  |g Vlada Aleksandrovna  |3 (RuTPU)RU\TPU\pers\47560 
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