Influence of Accidental Impurities on the Spectroscopic and Luminescent Properties of ZnWO4 Crystal; Materials; Vol. 16, iss. 7

Bibliographic Details
Parent link:Materials
Vol. 16, iss. 7.— 2023.— [2611, 17 p.]
Corporate Author: Национальный исследовательский Томский политехнический университет Инженерная школа новых производственных технологий Отделение материаловедения
Other Authors: Subbotin K. A. Kirill Anatoljevich, Titov A. I. Anatoly Igorevich, Solomatina V. A. Viktoriya Alekseevna, Dinu M. Mihaela, Khomyakov A. V. Andrey Vladimirovich, Pakina E. Ekaterina, Yakovlev V. Yu. Viktor Yurjevich, Valiev D. T. Damir Talgatovich, Zykova M. P. Marina Pavlovna, Kuleshova K. V. Kristina Vitaljevna, Didenko Ya. A. Yana Albertovna, Lis D. A. Denis Aleksandrovich, Grishechkin M. B. Mikhail Borisovich, Batygov S. Kh. Sergey Khacheturovich, Kuznetsov S. V. Sergey Viktorovich, Avetisov I. Kh. Igor Khristoforovich
Summary:Title screen
Special techniques for deep purification of ZnO and WO3 have been developed in this work. A ZnWO4 single crystal has been grown by the Czochralski method using purified ZnO and WO3 chemicals, along with the ZnWO4 crystal-etalon, which has been grown at the same conditions using commercially available 5N ZnO and WO3 chemicals. The actual accidental impurities compositions of both the initial chemicals and the grown crystals have been measured by inductively coupled plasma mass-spectrometry. A complex of comparative spectroscopic studies of the crystals has been performed, including optical absorption spectra, photo-, X-ray-, and cathodoluminescence spectra and decay kinetics, as well as the photoluminescence excitation spectra. The revealed differences in the measured properties of the crystals have been analyzed in terms of influence of the accidental impurities on these properties.
Language:English
Published: 2023
Subjects:
Online Access:http://earchive.tpu.ru/handle/11683/132653
https://doi.org/10.3390/ma16072611
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=669382

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330 |a Special techniques for deep purification of ZnO and WO3 have been developed in this work. A ZnWO4 single crystal has been grown by the Czochralski method using purified ZnO and WO3 chemicals, along with the ZnWO4 crystal-etalon, which has been grown at the same conditions using commercially available 5N ZnO and WO3 chemicals. The actual accidental impurities compositions of both the initial chemicals and the grown crystals have been measured by inductively coupled plasma mass-spectrometry. A complex of comparative spectroscopic studies of the crystals has been performed, including optical absorption spectra, photo-, X-ray-, and cathodoluminescence spectra and decay kinetics, as well as the photoluminescence excitation spectra. The revealed differences in the measured properties of the crystals have been analyzed in terms of influence of the accidental impurities on these properties. 
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