Aryl-, Akynyl-, and Alkenylbenziodoxoles: Synthesis and Synthetic Applications; Molecules; Vol. 28, iss. 5

Aryl-, Akynyl-, and Alkenylbenziodoxoles: Synthesis and Synthetic Applications; Molecules; Vol. 28, iss. 5

Bibliographische Detailangaben
Parent link:Molecules
Vol. 28, iss. 5.— 2023.— [2136, 44 p.]
Weitere Verfasser: Mironova I. A. Irina Andreevna, Noskov D. M. Dmitry Mikhaylovich, Yoshimura A. Akira, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Zhdankin V. V. Viktor Vladimirovich
Zusammenfassung:Title screen
Hypervalent iodine reagents are in high current demand due to their exceptional reactivity in oxidative transformations, as well as in diverse umpolung functionalization reactions. Cyclic hypervalent iodine compounds, known under the general name of benziodoxoles, possess improved thermal stability and synthetic versatility in comparison with their acyclic analogs. Aryl-, alkenyl-, and alkynylbenziodoxoles have recently received wide synthetic applications as efficient reagents for direct arylation, alkenylation, and alkynylation under mild reaction conditions, including transition metal-free conditions as well as photoredox and transition metal catalysis. Using these reagents, a plethora of valuable, hard-to-reach, and structurally diverse complex products can be synthesized by convenient procedures. The review covers the main aspects of the chemistry of benziodoxole-based aryl-, alkynyl-, and alkenyl- transfer reagents, including preparation and synthetic applications.
Sprache:Englisch
Veröffentlicht: 2023
Schlagworte:
труды учёных ТПУ
электронный ресурс
hypervalent iodine
functionalization
benziodoxoles
arylation
benzyne
alkynylation
vinylation
EBX
VBX
гипервалентный йод
функционализация
арилирование
бензины
алкинилирование
винилирование
Online-Zugang:https://doi.org/10.3390/molecules28052136
Format: Elektronisch Buchkapitel
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=669250

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