Aryl-, Akynyl-, and Alkenylbenziodoxoles: Synthesis and Synthetic Applications; Molecules; Vol. 28, iss. 5
| Parent link: | Molecules Vol. 28, iss. 5.— 2023.— [2136, 44 p.] |
|---|---|
| Outros Autores: | , , , , |
| Resumo: | Title screen Hypervalent iodine reagents are in high current demand due to their exceptional reactivity in oxidative transformations, as well as in diverse umpolung functionalization reactions. Cyclic hypervalent iodine compounds, known under the general name of benziodoxoles, possess improved thermal stability and synthetic versatility in comparison with their acyclic analogs. Aryl-, alkenyl-, and alkynylbenziodoxoles have recently received wide synthetic applications as efficient reagents for direct arylation, alkenylation, and alkynylation under mild reaction conditions, including transition metal-free conditions as well as photoredox and transition metal catalysis. Using these reagents, a plethora of valuable, hard-to-reach, and structurally diverse complex products can be synthesized by convenient procedures. The review covers the main aspects of the chemistry of benziodoxole-based aryl-, alkynyl-, and alkenyl- transfer reagents, including preparation and synthetic applications. |
| Idioma: | inglês |
| Publicado em: |
2023
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| Assuntos: | |
| Acesso em linha: | https://doi.org/10.3390/molecules28052136 |
| Formato: | Recurso Electrónico Capítulo de Livro |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=669250 |
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| 200 | 1 | |a Aryl-, Akynyl-, and Alkenylbenziodoxoles: Synthesis and Synthetic Applications |f I. A. Mironova, M. D. Noskov, A. Yoshimura [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 194 tit.] | ||
| 330 | |a Hypervalent iodine reagents are in high current demand due to their exceptional reactivity in oxidative transformations, as well as in diverse umpolung functionalization reactions. Cyclic hypervalent iodine compounds, known under the general name of benziodoxoles, possess improved thermal stability and synthetic versatility in comparison with their acyclic analogs. Aryl-, alkenyl-, and alkynylbenziodoxoles have recently received wide synthetic applications as efficient reagents for direct arylation, alkenylation, and alkynylation under mild reaction conditions, including transition metal-free conditions as well as photoredox and transition metal catalysis. Using these reagents, a plethora of valuable, hard-to-reach, and structurally diverse complex products can be synthesized by convenient procedures. The review covers the main aspects of the chemistry of benziodoxole-based aryl-, alkynyl-, and alkenyl- transfer reagents, including preparation and synthetic applications. | ||
| 461 | |t Molecules | ||
| 463 | |t Vol. 28, iss. 5 |v [2136, 44 p.] |d 2023 | ||
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| 610 | 1 | |a hypervalent iodine | |
| 610 | 1 | |a functionalization | |
| 610 | 1 | |a benziodoxoles | |
| 610 | 1 | |a arylation | |
| 610 | 1 | |a benzyne | |
| 610 | 1 | |a alkynylation | |
| 610 | 1 | |a vinylation | |
| 610 | 1 | |a EBX | |
| 610 | 1 | |a VBX | |
| 610 | 1 | |a гипервалентный йод | |
| 610 | 1 | |a функционализация | |
| 610 | 1 | |a арилирование | |
| 610 | 1 | |a бензины | |
| 610 | 1 | |a алкинилирование | |
| 610 | 1 | |a винилирование | |
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| 701 | 1 | |a Noskov |b D. M. |c chemical engineer |c Research Engineer of Tomsk Polytechnic University |f 1997- |g Dmitry Mikhaylovich |3 (RuTPU)RU\TPU\pers\31789 |9 89072 | |
| 701 | 1 | |a Yoshimura |b A. |c chemical engineer |c Professor of Tomsk Polytechnic University |f 1981- |g Akira |3 (RuTPU)RU\TPU\pers\39852 |9 21126 | |
| 701 | 1 | |a Yusubov |b M. S. |c chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1961- |g Mekhman Suleiman-Ogly (Suleimanovich) |3 (RuTPU)RU\TPU\pers\31833 |9 15928 | |
| 701 | 1 | |a Zhdankin |b V. V. |c chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1956- |g Viktor Vladimirovich |3 (RuTPU)RU\TPU\pers\35758 |9 18915 | |
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