Ion and Water Molecule Distribution over Illite Particle Surface

Ion and Water Molecule Distribution over Illite Particle Surface

Bibliografiske detaljer
Parent link:	Russian Physics Journal Vol. 65, iss. 4.— 2022.— [P. 605-609]
Institution som forfatter:	Национальный исследовательский Томский политехнический университет Инженерная школа ядерных технологий Отделение ядерно-топливного цикла
Andre forfattere:	Myshkin (Mishkin) V. F. Vyacheslav Fedorovich, Wang Cailun, Khan V. A. Valery Alekseevich, Baraban A. P. Aleksandr Petrovich, Poberezhnikov A. D. Andrey Dmitrievich, Shukshina D. D. Darjya Dmitrievna
Summary:	Title screen The paper investigates the diffusion of Na+ and Cl? in a pore liquid between illite microparticles using the quantum-chemical modeling in Materials Studio. The potential distribution induced by the surface charge of the clay mineral layer, disturbs the uniform distribution of cations and anions observed in the bulk solution. As a result, a layer of immobile cations appears near the microparticle surface. As the distance from the surface grows, the anion concentration grows also, while the potential decreases down to zero. In the appeared double-electric layer, the cation diffusion conditions differ. The particle migration rate in the outer surface of the illite microparticle decreases sequentially for water, anion, cation. Режим доступа: по договору с организацией-держателем ресурса
Sprog:	engelsk
Udgivet:	2022
Fag:	электронный ресурс труды учёных ТПУ illite crystallite external diffusion cation anion water radial distribution function
Online adgang:	https://doi.org/10.1007/s11182-022-02675-5
Format:	Electronisk Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=669169

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