Two-Dimensional Zeolitic Imidazolate Framework ZIF-L: A Promising Catalyst for Polymerization; Catalysts; Vol. 12 iss. 5

Two-Dimensional Zeolitic Imidazolate Framework ZIF-L: A Promising Catalyst for Polymerization; Catalysts; Vol. 12 iss. 5

Chi tiết về thư mục
Parent link:	Catalysts Vol. 12 iss. 5.— 2022.— [521, 12 p.]
Tác giả của công ty:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
Tác giả khác:	Rahaman M. A. Md Abdur, Mousavi B. Bibimaryam, Naz F. Farah, Verpoort F. V. K. Frensis Valter Kornelius
Tóm tắt:	Title screen Here, for the first time, a 2D and leaf-like zeolitic imidazolate framework (ZIF-L) is reported for the synthesis of ultrahigh molecular weight (UHMW) poly(methyl methacrylate) (PMMA) with Mn up to 1390 kg mol?1. This synthesis method is a one-step process without any co-catalyst in a solvent-free medium. SEM, PXRD, FT-IR, TGA, and nitrogen sorption measurements confirmed the 2D and leaf-like structure of ZIF-L. The results of PXRD, SEM, TGA demonstrate that the catalyst ZIF-L is remarkably stable even after a long-time polymerization reaction. Zwitterionic Lewis pair polymerization (LPP) has been proposed for the catalytic performance of ZIF-L on methyl methacrylate (MMA) polymerization. This MMA polymerization is consistent with a living system, where ZIF-L could reinitiate the polymerization and propagates the process by gradually growing the polymer chains.
Ngôn ngữ:	Tiếng Anh
Được phát hành:	2022
Những chủ đề:	электронный ресурс труды учёных ТПУ ultrahigh molecular weight polymer poly methyl methacrylate heterogeneous catalyst zeolitic imidozolate framework
Truy cập trực tuyến:	https://doi.org/10.3390/catal12050521
Định dạng:	Điện tử Chương của sách
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=668911

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