Metal Embedded Porous Carbon for Efficient CO2 Cycloaddition under Mild Conditions; Catalysts; Vol. 12 iss. 4

Metal Embedded Porous Carbon for Efficient CO2 Cycloaddition under Mild Conditions; Catalysts; Vol. 12 iss. 4

Bibliographic Details
Parent link:Catalysts
Vol. 12 iss. 4.— 2022.— [427, 15 p.]
Corporate Author: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
Other Authors: Chen Qi, Chaemchuen Somboon, Liu Meng, Wang Jichao, Zhuiykov S. Serge, Verpoort F. V. K. Frensis Valter Kornelius
Summary:Title screen
Nitrogen-doped porous carbon material was generated via thermal pyrolysis of zeolitic imidazole frameworks (ZIFs). The structure of the ZIF templates was tuned, so that the obtained product was an N-doped porous carbon-containing encapsulated metal nanoparticle. The hierarchical structural and unique properties of pyrolyzed materials are involved in further application, including catalysis. The as-synthesized porous carbon materials were applied as a catalyst for CO2 fixation on cyclic carbonates under near ambient pressure without solvent and co-catalyst. The zinc dispersion in highly porous carbon material, deriving from ZIF-8, exhibited a superior catalytic performance among the synthesized materials. The acid sites (Zn species) and the incorporated basic sites (N-species) present in the porous carbon material are essential for a high affinity for gas adsorption and CO2 conversion. Additionally, the catalyst was found to be very robust and stable during recycling studies as the catalytic performance remained high for seven cycles.
Language:English
Published: 2022
Subjects:
электронный ресурс
труды учёных ТПУ
N-doped carbon
ZIFs
catalysis
pyrolysis
CO2 utilization
Online Access:https://doi.org/10.3390/catal12040427
Format: MixedMaterials Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=668879

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