2,4,5,6-Substituted 4,5-dihydro-1,2,4,5-tetrazin-3(2H)-ones as non-classical initiators of controlled radical polymerization of styrene
| Parent link: | Russian Chemical Bulletin Vol. 71, iss. 7.— 2022.— [P. 1549-1554] |
|---|---|
| Institution som forfatter: | |
| Andre forfattere: | , , , , , , |
| Summary: | Title screen A series of 2,4,5,6-substituted 4,5-dihydro-1,2,4,5-terazin-3(2H)-ones are studied as initiators of controlled radical polymerization of styrene at 100 and 120 °C. It has been established that not only electronic effects of substituents, but also other factors have a significant effect on the process, including the probability of side reactions of the verdazyl radical with the monomer, but not with the growing chain. In the course of experiments, high molecular weight polystyrene was obtained in a short time at moderate temperatures, which indicates high prospects for the use of verdazyl-based initiators in the controlled polymerization of olefins. Режим доступа: по договору с организацией-держателем ресурса |
| Sprog: | engelsk |
| Udgivet: |
2022
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| Fag: | |
| Online adgang: | https://doi.org/10.1007/s11172-022-3563-6 |
| Format: | Electronisk Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=668772 |
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| 200 | 1 | |a 2,4,5,6-Substituted 4,5-dihydro-1,2,4,5-tetrazin-3(2H)-ones as non-classical initiators of controlled radical polymerization of styrene |d 2,4,5,6-Замещенные-4,5-дигидро-1,2,4,5-тетразин-3(2H)-оны как неклассические инициаторы контролируемой радикальной полимеризации стирола |f D. E. Votkina, M. Rollet, M. E. Trusova [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 15 tit.] | ||
| 330 | |a A series of 2,4,5,6-substituted 4,5-dihydro-1,2,4,5-terazin-3(2H)-ones are studied as initiators of controlled radical polymerization of styrene at 100 and 120 °C. It has been established that not only electronic effects of substituents, but also other factors have a significant effect on the process, including the probability of side reactions of the verdazyl radical with the monomer, but not with the growing chain. In the course of experiments, high molecular weight polystyrene was obtained in a short time at moderate temperatures, which indicates high prospects for the use of verdazyl-based initiators in the controlled polymerization of olefins. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Russian Chemical Bulletin | ||
| 463 | |t Vol. 71, iss. 7 |v [P. 1549-1554] |d 2022 | ||
| 510 | 1 | |a 2,4,5,6-Замещенные-4,5-дигидро-1,2,4,5-тетразин-3(2H)-оны как неклассические инициаторы контролируемой радикальной полимеризации стирола |z rus | |
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a 6-oxoverdazyl radicals | |
| 610 | 1 | |a controlled radical polymerization | |
| 610 | 1 | |a polystyrene | |
| 701 | 1 | |a Votkina |b D. E. |c chemical engineer |c Associate Scientist of the Tomsk Polytechnic University |f 1995- |g Darjya Evgenjevna |3 (RuTPU)RU\TPU\pers\45598 |9 21944 | |
| 701 | 1 | |a Rollet |b M. | |
| 701 | 1 | |a Trusova |b M. E. |c organic chemist |c Associate professor of Tomsk Polytechnic University, Candidate of chemical sciences |f 1982- |g Marina Evgenievna |3 (RuTPU)RU\TPU\pers\31823 |9 15918 | |
| 701 | 1 | |a Audran |b G. |g Gerard | |
| 701 | 1 | |a Marque |b S. R. A. |g Sylvain R. A. | |
| 701 | 1 | |a Petunin |b P. V. |c chemist |c Associate Professor of Tomsk Polytechnic University, Candidate of Chemical Sciences |f 1982- |g Pavel Vasilievich |3 (RuTPU)RU\TPU\pers\36904 |9 19933 | |
| 701 | 1 | |a Postnikov |b P. S. |c organic chemist |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences |f 1984- |g Pavel Sergeevich |3 (RuTPU)RU\TPU\pers\31287 |9 15465 | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Исследовательская школа химических и биомедицинских технологий |c (2017- ) |3 (RuTPU)RU\TPU\col\23537 |
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