Cold-seep carbonates of the Laptev Sea continental slope: Constraints from fluid sources and environment of formation
| Parent link: | Chemical Geology Vol. 610.— 2022.— [121103, 13 p.] |
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| Ente Autore: | |
| Altri autori: | , , , , , |
| Riassunto: | Title screen This study presents results of the petrographic, mineralogical, stable isotopes of oxygen and carbon, and trace element investigation of authigenic carbonates collected at newly discovered active cold seeps on the Laptev Sea continental slope at ∼300 m water depth. These carbonates are mainly represented by Mg-calcite with MgCO3 content from 9.1 mol% to 14.0 mol%. The low δ13C values of carbonates ranging from −50.6 ‰ to −32.4 ‰ (V-PDB) indicate that they were formed from anaerobic oxidation of biogenic methane and minor participation of other carbon sources. The difference between measured (from 4.7 ‰ to 5.5 ‰) and calculated (4.0 ‰) δ18Ocarb values might be inherited from fluids enriched in 18O due to dissociation of gas hydrates, which could be the source of methane. The carbonates exhibit weak enrichment in Co, moderate and strong enrichments in As, Mo, and Sb, and strong enrichment in U. Interestingly, As, Sb, and Co correlate with the pyrite content. This indicates that authigenic iron sulfides promote the immobilization of these redox-sensitive elements in seep sediments. The (Mo/U)EF values and anomalies of concentration of Mo and U probably indicate variations in the redox conditions during carbonate formation due to episodically seepage activity changes. Ascending methane-bearing fluids were the main contributor to the enrichment of cold-seep carbonates in As, Mo, Sb, and U at the Laptev Sea continental slope. However additional input from the particulate shuttle process can not be ruled out. Режим доступа: по договору с организацией-держателем ресурса |
| Lingua: | inglese |
| Pubblicazione: |
2022
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| Soggetti: | |
| Accesso online: | https://doi.org/10.1016/j.chemgeo.2022.121103 |
| Natura: | Elettronico Capitolo di libro |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=668683 |
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| 200 | 1 | |a Cold-seep carbonates of the Laptev Sea continental slope: Constraints from fluid sources and environment of formation |f A. S. Ruban, M. A. Rudmin, A. K. Mazurov [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 330 | |a This study presents results of the petrographic, mineralogical, stable isotopes of oxygen and carbon, and trace element investigation of authigenic carbonates collected at newly discovered active cold seeps on the Laptev Sea continental slope at ∼300 m water depth. These carbonates are mainly represented by Mg-calcite with MgCO3 content from 9.1 mol% to 14.0 mol%. The low δ13C values of carbonates ranging from −50.6 ‰ to −32.4 ‰ (V-PDB) indicate that they were formed from anaerobic oxidation of biogenic methane and minor participation of other carbon sources. The difference between measured (from 4.7 ‰ to 5.5 ‰) and calculated (4.0 ‰) δ18Ocarb values might be inherited from fluids enriched in 18O due to dissociation of gas hydrates, which could be the source of methane. The carbonates exhibit weak enrichment in Co, moderate and strong enrichments in As, Mo, and Sb, and strong enrichment in U. Interestingly, As, Sb, and Co correlate with the pyrite content. This indicates that authigenic iron sulfides promote the immobilization of these redox-sensitive elements in seep sediments. The (Mo/U)EF values and anomalies of concentration of Mo and U probably indicate variations in the redox conditions during carbonate formation due to episodically seepage activity changes. Ascending methane-bearing fluids were the main contributor to the enrichment of cold-seep carbonates in As, Mo, Sb, and U at the Laptev Sea continental slope. However additional input from the particulate shuttle process can not be ruled out. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Chemical Geology | ||
| 463 | |t Vol. 610 |v [121103, 13 p.] |d 2022 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a authigenic carbonates | |
| 610 | 1 | |a cold seep | |
| 610 | 1 | |a stable oxygen and carbon isotopes | |
| 610 | 1 | |a trace element enrichments | |
| 610 | 1 | |a redox conditions | |
| 610 | 1 | |a Laptev Sea | |
| 701 | 1 | |a Ruban |b A. S. |c geologist |c engineer of Tomsk Polytechnic University |f 1991- |g Aleksey Sergeevich |3 (RuTPU)RU\TPU\pers\34023 |9 17590 | |
| 701 | 1 | |a Rudmin |b M. A. |c geologist |c Associate Professor of Tomsk Polytechnic University, Candidate of Geological and Mineralogical Sciences |f 1989- |g Maksim Andreevich |3 (RuTPU)RU\TPU\pers\33254 |9 16999 | |
| 701 | 1 | |a Mazurov |b A. K. |c geologist |c Professor-consultant of Tomsk Polytechnic University, Doctor of Geological and Mineralogical Sciences |f 1951- |g Aleksey Karpovich |3 (RuTPU)RU\TPU\pers\30165 |9 14563 | |
| 701 | 1 | |a Chernykh |b D. V. |c geologist |c engineer at Tomsk Polytechnic University, candidate of technical Sciences |f 1988- |g Denis Vyacheslavovich |3 (RuTPU)RU\TPU\pers\35528 | |
| 701 | 1 | |a Dudarev |b O. V. |c geologist |c researcher of Tomsk Polytechnic University, candidate of geological and mineralogical Sciences |f 1955- |g Oleg Viktorovich |3 (RuTPU)RU\TPU\pers\35379 | |
| 701 | 1 | |a Semiletov |b I. P. |c geographer |c Professor of Tomsk Polytechnic University, doctor of geographical Sciences |f 1955- |g Igor Petrovich |3 (RuTPU)RU\TPU\pers\34220 | |
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