Hypervalent Iodine-Mediated Azidation Reactions; European Journal of Organic Chemistry; Vol. 2022, iss. 34

Hypervalent Iodine-Mediated Azidation Reactions; European Journal of Organic Chemistry; Vol. 2022, iss. 34

গ্রন্থ-পঞ্জীর বিবরন
Parent link:	European Journal of Organic Chemistry Vol. 2022, iss. 34.— 2022.— [e202200754, 24 p.]
সংস্থা লেখক:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
অন্যান্য লেখক:	Mironova I. A. Irina Andreevna, Kirsch S. F., Zhdankin V. V. Viktor Vladimirovich, Yoshimura A. Akira, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich)
সংক্ষিপ্ত:	Title screen Organic azides have found wide application in various fields of science and technology. This review summarizes recently developed approaches to the direct, one-step synthesis of diverse organic azides utilizing hypervalent iodine reagents. The first part of review deals with the azidation using unstable azidoiodinanes generated in situ from common hypervalent iodine reagents (such as diacetoxyiodobenzene or iodosylbenzene) and a source of azide anion (TMSN3 or NaN3). The second part of review is dedicated to the application of stable azidobenziodoxoles as useful azidating reagents that allow selective direct azidation of C?H bonds or double carbon-carbon bonds under mild reaction conditions. The use of azidobenziodoxoles eliminates the main disadvantages of the traditional approaches to organic azides, such as the need in pre-functionalization of organic substrates and harsh reaction conditions. Synthetic application of azidobenziodoxoles made possible direct selective azidation of a plethora of organic substrates including complex molecules at the late synthetic stage.
ভাষা:	ইংরেজি
প্রকাশিত:	2022
বিষয়গুলি:	электронный ресурс труды учёных ТПУ azide azidation hypervalent compounds hypervalent iodine iodine азиды гипервалентные соединения гипервалентный йод
অনলাইন ব্যবহার করুন:	https://doi.org/10.1002/ejoc.202200754
বিন্যাস:	বৈদ্যুতিক গ্রন্থের অধ্যায়
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=668675

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