Gram-scale synthesis of carboxylic acids via catalytic acceptorless dehydrogenative coupling of alcohols and hydroxides at an ultralow Ru loading

Gram-scale synthesis of carboxylic acids via catalytic acceptorless dehydrogenative coupling of alcohols and hydroxides at an ultralow Ru loading

書誌詳細
Parent link:	Applied Catalysis A: General Vol. 630.— 2022.— [118443, 12 p.]
団体著者:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
その他の著者:	Wu Zhe, Zhi-Qin Wang, Cheng Hua, Zheng Zhong-Hui, Yuan Ye, Chen Cheng E. Elkadi, Verpoort F. V. K. Frensis Valter Kornelius
要約:	Title screen Acceptorless dehydrogenative coupling (ADC) of alcohols and water/hydroxides is an emergent and graceful approach to produce carboxylic acids. Therefore, it is of high demand to develop active and practical catalysts/catalytic systems for this attractive transformation. Herein, we designed and fabricated a series of cyclometallated N-heterocyclic carbene-Ru (NHC-Ru) complexes via ligand tuning of [Ru-1], the superior complex in our previous work. Gratifyingly, gram-scale synthesis of carboxylic acids was efficiently enabled at an ultralow Ru loading (62.5 ppm) in open air. Moreover, effects of distinct ancillary NHC ligands and other parameters on this catalytic process were thoroughly studied, while further systematic studies were carried out to provide rationales for the activity trend of [Ru-1]-[Ru-7]. Finally, determination of quantitative green metrics illustrated that the present work exhibited superiority over representative literature reports. Hopefully, this study could provide valuable input for researchers who are engaging in metal-catalyzed ADC reactions. Режим доступа: по договору с организацией-держателем ресурса
言語:	英語
出版事項:	2022
主題:	электронный ресурс труды учёных ТПУ gram-scale synthesis carboxylic acids Acceptorless dehydrogenative coupling (ADC) N-heterocyclic carbene-Ru (NHC-Ru) ultralow loading синтез карбоновые кислоты N-гетероциклические карбены сверхнизкие давления
オンライン･アクセス:	https://doi.org/10.1016/j.apcata.2021.118443
フォーマット:	電子媒体図書の章
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=668559

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