Composition of Rhenium Heptasulfide Prepared by Different Methods

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Parent link:Inorganic Materials.— : Springer Nature
Vol. 58, iss. 9.— 2022.— P. 899-905
Príomhchruthaitheoir: Egorov N. B. Nikolai Borisovich
Rannpháirtithe: Isaeva E. A. Evgeniya Andreevna
Achoimre:Title screen
Re2S7 samples have been synthesized by thiosulfate, sulfide. and thioacetamide processes and shown to differ very little in composition. Their composition has been determined by chemical analysis, IR spectroscopy, and X-ray photoelectron spectroscopy (XPS). According to chemical analysis data, the samples contain an excess of sulfur compared to the stoichiometric composition Re2S7. According to IR spectroscopy results, the synthesized Re2S7 samples contain water, hydrogen sulfate ions, and thioperrhenate ions. XPS results demonstrate the presence of sulfide, disulfide, and sulfate ions on the surface of Re2S7. In addition, the rhenium in the synthesized samples is in an odd oxidation state. Possible causes of distinctions between the structural models of Re2S7 proposed in the literature are discussed
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AM_Agreement
Teanga:Béarla
Foilsithe / Cruthaithe: 2022
Ábhair:
Rochtain ar líne:https://doi.org/10.1134/S0020168522090047
Статья на русском языке
Formáid: Leictreonach Caibidil leabhair
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=668475
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