Low-temperature method for desiliconization of polymetallic slags by ammonium bifluoride solution

Dettagli Bibliografici
Parent link:Environmental Science and Pollution Research (ESPR)
Vol. 30, iss. 11.— 2023.— [P. 30271–30280]
Ente Autore: Национальный исследовательский Томский политехнический университет Инженерная школа ядерных технологий Отделение ядерно-топливного цикла
Altri autori: Smorokov A. A. Andrey Arkadievich, Kantaev A. S. Aleksandr Sergeevich, Bryankin D. V. Daniel Valerievich, Miklashevich A. Anna, Kamarou M. Maksim, Romanovski V. Valentin
Riassunto:Title screen
Throughout the period of operation of non-ferrous metal deposits, a significant amount of waste has been accumulated. The accumulated waste contains valuable metals in concentrations that allow considering them as valuable raw materials. However, it is worth noticing the presence of problems that previously did not allow for more complete extraction of the target components. Such problems include the presence of significant amounts of silicon dioxide in the form of a silicate matrix, the removal of which will allow the extraction of valuable components with the elimination of industrial waste areas. The paper considers a method for removing silicon from the polymetallic slags. According to the results of the work, it was found that silicon passes into solution in the form of ammonium hexafluorosilicate. Iron, aluminum, and a number of other components react with ammonium hydrofluoride, but do not leach into the solution due to their low solubility in the resulting system. After removing silicon, the solid residue was subjected to pyrohydrolysis to obtain a product that can be subjected to magnetic separation to obtain a magnetic iron concentrate and a non-ferrous metal concentrate. The formed concentrate can later be used to extract zinc, lead, silver, etc. The productive solution was directed to the deposition of silicon with the subsequent production of silicon dioxide. The resulting solution can be directed to evaporation in order to regenerate and reuse ammonium hydrodifluoride.
Режим доступа: по договору с организацией-держателем ресурса
Lingua:inglese
Pubblicazione: 2023
Soggetti:
Accesso online:https://doi.org/10.1007/s11356-022-24230-y
Natura: Elettronico Capitolo di libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=668457

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200 1 |a Low-temperature method for desiliconization of polymetallic slags by ammonium bifluoride solution  |f A. A. Smorokov, A. S. Kantaev, D. V. Bryankin [et al.] 
203 |a Text  |c electronic 
300 |a Title screen 
320 |a [References: 43 tit.] 
330 |a Throughout the period of operation of non-ferrous metal deposits, a significant amount of waste has been accumulated. The accumulated waste contains valuable metals in concentrations that allow considering them as valuable raw materials. However, it is worth noticing the presence of problems that previously did not allow for more complete extraction of the target components. Such problems include the presence of significant amounts of silicon dioxide in the form of a silicate matrix, the removal of which will allow the extraction of valuable components with the elimination of industrial waste areas. The paper considers a method for removing silicon from the polymetallic slags. According to the results of the work, it was found that silicon passes into solution in the form of ammonium hexafluorosilicate. Iron, aluminum, and a number of other components react with ammonium hydrofluoride, but do not leach into the solution due to their low solubility in the resulting system. After removing silicon, the solid residue was subjected to pyrohydrolysis to obtain a product that can be subjected to magnetic separation to obtain a magnetic iron concentrate and a non-ferrous metal concentrate. The formed concentrate can later be used to extract zinc, lead, silver, etc. The productive solution was directed to the deposition of silicon with the subsequent production of silicon dioxide. The resulting solution can be directed to evaporation in order to regenerate and reuse ammonium hydrodifluoride. 
333 |a Режим доступа: по договору с организацией-держателем ресурса 
461 |t Environmental Science and Pollution Research (ESPR) 
463 |t Vol. 30, iss. 11  |v [P. 30271–30280]  |d 2023 
610 1 |a электронный ресурс 
610 1 |a труды учёных ТПУ 
610 1 |a ammonium bifluoride 
610 1 |a polymetallic slag 
610 1 |a silicon dioxide 
610 1 |a low-temperature desiliconization 
610 1 |a бифторид аммония 
610 1 |a шлаки 
610 1 |a диоксид кремния 
610 1 |a низкотемпературное обескремнивание 
701 1 |a Smorokov  |b A. A.  |c chemical engineer  |c Senior Lecturer, Associate Scientist of Tomsk Polytechnic University  |f 1993-  |g Andrey Arkadievich  |3 (RuTPU)RU\TPU\pers\33850  |9 17439 
701 1 |a Kantaev  |b A. S.  |c chemical engineer  |c Associate Professor of Tomsk Polytechnic University, Candidate of Sciences  |f 1981-  |g Aleksandr Sergeevich  |3 (RuTPU)RU\TPU\pers\32622  |9 16534 
701 1 |a Bryankin  |b D. V.  |c Chemist  |c laboratory assistant researcher of Tomsk Polytechnic University  |f 2000-  |g Daniel Valerievich  |3 (RuTPU)RU\TPU\pers\47200 
701 1 |a Miklashevich  |b A.  |g Anna 
701 1 |a Kamarou  |b M.  |g Maksim 
701 1 |a Romanovski  |b V.  |g Valentin 
712 0 2 |a Национальный исследовательский Томский политехнический университет  |b Инженерная школа ядерных технологий  |b Отделение ядерно-топливного цикла  |3 (RuTPU)RU\TPU\col\23554 
801 0 |a RU  |b 63413507  |c 20230320  |g RCR 
856 4 |u https://doi.org/10.1007/s11356-022-24230-y 
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