Hybrid biodegradable electrospun scaffolds based on poly(l-lactic acid) and reduced graphene oxide with improved piezoelectric response
| Parent link: | Polymer Journal Vol. X, iss. XX.— 2022.— [16 p.] |
|---|---|
| Corporate Author: | |
| Other Authors: | , , , , , , , , , |
| Summary: | Title screen Piezoelectric poly-L-lactide (PLLA) is a biodegradable polymer used in various biomedical applications. However, tailoring and controlling the structure of PLLA to enhance its piezoelectric response remains a challenge. In this work, extensive characterization was performed to reveal the effect of the reduced graphene oxide (rGO) content (0.2, 0.7, and 1.0 wt%) on the morphology, structure, thermal and piezoelectric behavior of PLLA scaffolds. Randomly oriented homogeneous fibers and a quasi-amorphous structure for pure PLLA and hybrid PLLA-rGO scaffolds were revealed. The addition of rGO affected the molecular structure of the PLLA scaffolds: for example, the number of polar C=O functional groups was increased. Increasing the content of rGO to 1 wt% resulted in decreased glass transition and melting temperatures and increased the degree of crystallinity of the scaffolds. The addition of 0.2 wt% rGO enhanced the effective local vertical and lateral piezoresponses by 2.3 and 15.4 times, respectively, in comparison with pure PLLA fibers. The presence of the shear piezoelectric a-phase (P212121) in uniaxially oriented PLLA fibers and C=O bond rotation in the polymer chains explained the observed piezoresponse. Thus, this study revealed routes to prepare hybrid biodegradable scaffolds with enhanced piezoresponse for tissue engineering applications. Режим доступа: по договору с организацией-держателем ресурса |
| Language: | English |
| Published: |
2022
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| Subjects: | |
| Online Access: | https://doi.org/10.1038/s41428-022-00669-1 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=668264 |
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| 200 | 1 | |a Hybrid biodegradable electrospun scaffolds based on poly(l-lactic acid) and reduced graphene oxide with improved piezoelectric response |f I. O. Pary (Pariy), R. V. Chernozem, P. V. Chernozem [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 129 tit.] | ||
| 330 | |a Piezoelectric poly-L-lactide (PLLA) is a biodegradable polymer used in various biomedical applications. However, tailoring and controlling the structure of PLLA to enhance its piezoelectric response remains a challenge. In this work, extensive characterization was performed to reveal the effect of the reduced graphene oxide (rGO) content (0.2, 0.7, and 1.0 wt%) on the morphology, structure, thermal and piezoelectric behavior of PLLA scaffolds. Randomly oriented homogeneous fibers and a quasi-amorphous structure for pure PLLA and hybrid PLLA-rGO scaffolds were revealed. The addition of rGO affected the molecular structure of the PLLA scaffolds: for example, the number of polar C=O functional groups was increased. Increasing the content of rGO to 1 wt% resulted in decreased glass transition and melting temperatures and increased the degree of crystallinity of the scaffolds. The addition of 0.2 wt% rGO enhanced the effective local vertical and lateral piezoresponses by 2.3 and 15.4 times, respectively, in comparison with pure PLLA fibers. The presence of the shear piezoelectric a-phase (P212121) in uniaxially oriented PLLA fibers and C=O bond rotation in the polymer chains explained the observed piezoresponse. Thus, this study revealed routes to prepare hybrid biodegradable scaffolds with enhanced piezoresponse for tissue engineering applications. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Polymer Journal | ||
| 463 | |t Vol. X, iss. XX |v [16 p.] |d 2022 | ||
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| 610 | 1 | |a physics | |
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| 701 | 1 | |a Pary (Pariy) |b I. O. |c physicist |c engineer of Tomsk Polytechnic University |f 1995- |g Igor Olegovich |3 (RuTPU)RU\TPU\pers\45219 | |
| 701 | 1 | |a Chernozem |b R. V. |c physicist |c Associate Professor of Tomsk Polytechnic University |f 1992- |g Roman Viktorovich |3 (RuTPU)RU\TPU\pers\36450 |9 19499 | |
| 701 | 1 | |a Chernozem |b P. V. |c specialist in the field of informatics and computer technology |c Research Engineer of Tomsk Polytechnic University |f 1997- |g Polina Viktorovna |3 (RuTPU)RU\TPU\pers\47140 |9 22733 | |
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| 701 | 1 | |a Shvartsman |b V. V. |g Vladimir | |
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| 701 | 1 | |a Mathur |b S. |g Sanjay | |
| 701 | 1 | |a Surmenev |b R. A. |c physicist |c Associate Professor of Tomsk Polytechnic University, Senior researcher, Candidate of physical and mathematical sciences |f 1982- |g Roman Anatolievich |3 (RuTPU)RU\TPU\pers\31885 |9 15957 | |
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