Green Synthesis of 2-Oxazolidinones by an Efficient and Recyclable CuBr/Ionic Liquid System via CO2, Propargylic Alcohols, and 2-Aminoethanols; Catalysts; Vol. 11, iss. 2
| Parent link: | Catalysts Vol. 11, iss. 2.— 2021.— [233, 11 p.] |
|---|---|
| 団体著者: | Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий |
| その他の著者: | Chao Bu, Gong Yanyan, Minchen Du, Cheng Chen, Chaemchuen Somboon, Jia Hu, Yongxing Zhang, Velazquez H. D. Heriberto Diaz, Yuan Ye, Verpoort F. V. K. Frensis Valter Kornelius |
| 要約: | Title screen With the aim of profitable conversion of carbon dioxide (CO2) in an efficient, economical, and sustainable manner, we developed a CuBr/ionic liquid (1-butyl-3-methylimidazolium acetate) catalytic system that could efficiently catalyze the three-component reactions of propargylic alcohols, 2-aminoethanols, and CO2 to produce 2-oxazolidinones and ?-hydroxy ketones. Remarkably, this catalytic system employed lower metal loading (0.0125–0.5 mol%) but exhibited the highest turnover number (2960) ever reported, demonstrating its excellent activity and sustainability. Moreover, our catalytic system could efficiently work under 1 atm of CO2 pressure and recycle among the metal-catalyzed systems. |
| 言語: | 英語 |
| 出版事項: |
2021
|
| 主題: | |
| オンライン・アクセス: | https://doi.org/10.3390/catal11020233 |
| フォーマット: | 電子媒体 図書の章 |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=668015 |
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