Green Synthesis of 2-Oxazolidinones by an Efficient and Recyclable CuBr/Ionic Liquid System via CO2, Propargylic Alcohols, and 2-Aminoethanols; Catalysts; Vol. 11, iss. 2

গ্রন্থ-পঞ্জীর বিবরন
Parent link:Catalysts
Vol. 11, iss. 2.— 2021.— [233, 11 p.]
সংস্থা লেখক: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
অন্যান্য লেখক: Chao Bu, Gong Yanyan, Minchen Du, Cheng Chen, Chaemchuen Somboon, Jia Hu, Yongxing Zhang, Velazquez H. D. Heriberto Diaz, Yuan Ye, Verpoort F. V. K. Frensis Valter Kornelius
সংক্ষিপ্ত:Title screen
With the aim of profitable conversion of carbon dioxide (CO2) in an efficient, economical, and sustainable manner, we developed a CuBr/ionic liquid (1-butyl-3-methylimidazolium acetate) catalytic system that could efficiently catalyze the three-component reactions of propargylic alcohols, 2-aminoethanols, and CO2 to produce 2-oxazolidinones and ?-hydroxy ketones. Remarkably, this catalytic system employed lower metal loading (0.0125–0.5 mol%) but exhibited the highest turnover number (2960) ever reported, demonstrating its excellent activity and sustainability. Moreover, our catalytic system could efficiently work under 1 atm of CO2 pressure and recycle among the metal-catalyzed systems.
ভাষা:ইংরেজি
প্রকাশিত: 2021
বিষয়গুলি:
অনলাইন ব্যবহার করুন:https://doi.org/10.3390/catal11020233
বিন্যাস: বৈদ্যুতিক গ্রন্থের অধ্যায়
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=668015