Black Swan in Phase Transfer Catalysis: Influence of Mixing Mode on the Stereoselectivity of Glycosylation

Bibliographic Details
Parent link:	European Journal of Organic Chemistry Vol. 2022, iss. 14.— 2022.— [e202101377, 9 p.]
Corporate Author:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
Other Authors:	Myachin I. V. Iljya, Mamirgova Z. Zarina, Stepanova E. V. Elena Vladimirovna, Zinin A. I. Aleksandr Ivanovich, Chizhov A. O. Aleksandr Olegovich, Kononov L. O. Leonid Olegovich
Summary:	Title screen The influence of mixing mode on the outcome of the glycosylation under phase transfer conditions (batch vs flow) is found to be more complicated than it is generally assumed. A change in the way reagents are mixed leads not only to the enhanced mass transfer and consequently higher yield but also to a change in reaction mechanism.
Language:	English
Published:	2022
Subjects:	электронный ресурс труды учёных ТПУ стереоселективность гликозилирование смешение реагенты массообмен катализ фазовый перенос
Online Access:	https://doi.org/10.1002/ejoc.202101377
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=667925

Description
Summary:	Title screen The influence of mixing mode on the outcome of the glycosylation under phase transfer conditions (batch vs flow) is found to be more complicated than it is generally assumed. A change in the way reagents are mixed leads not only to the enhanced mass transfer and consequently higher yield but also to a change in reaction mechanism.
DOI:	10.1002/ejoc.202101377

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