Synthesis and characterization of a novel latent ring-opening metathesis polymerization catalyst

Detalhes bibliográficos
Parent link:Tetrahedron Letters
Vol. 84.— 2021.— [153451, 4 p.]
Autor Corporativo: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
Outros Autores: Sherstobitov I. A. Ivan Anatoljevich, Kiselev S. A. Stanislav Anatoljevich, Lyapkov A. A. Aleksey Alekseevich, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Zhdankin V. V. Viktor Vladimirovich, Bao-Yi Y. Yu, Verpoort F. V. K. Frensis Valter Kornelius
Resumo:Title screen
The synthesis and characterization of a novel latent ruthenium catalyst bearing a chelate ligand containing an oxadiazole fragment for the olefin metathesis are described. The main advantages of the utilization of this ligand are the straightforwardness of preparation, mild reaction conditions, and availability of the feedstock. Preliminary study of the catalytic activity of the Ru complex for metathesis reactions demonstrated its inactive nature for the ring-closing metathesis (RCM), but an excellent thermo-switchability for the ring-opening metathesis polymerization of norbornene.
Режим доступа: по договору с организацией-держателем ресурса
Idioma:inglês
Publicado em: 2021
Assuntos:
Acesso em linha:https://doi.org/10.1016/j.tetlet.2021.153451
Formato: Recurso Electrónico Capítulo de Livro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=667892

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