Synthesis and characterization of a novel latent ring-opening metathesis polymerization catalyst; Tetrahedron Letters; Vol. 84

Synthesis and characterization of a novel latent ring-opening metathesis polymerization catalyst; Tetrahedron Letters; Vol. 84

Bibliographic Details
Parent link:Tetrahedron Letters
Vol. 84.— 2021.— [153451, 4 p.]
Corporate Author: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
Other Authors: Sherstobitov I. A. Ivan Anatoljevich, Kiselev S. A. Stanislav Anatoljevich, Lyapkov A. A. Aleksey Alekseevich, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Zhdankin V. V. Viktor Vladimirovich, Bao-Yi Y. Yu, Verpoort F. V. K. Frensis Valter Kornelius
Summary:Title screen
The synthesis and characterization of a novel latent ruthenium catalyst bearing a chelate ligand containing an oxadiazole fragment for the olefin metathesis are described. The main advantages of the utilization of this ligand are the straightforwardness of preparation, mild reaction conditions, and availability of the feedstock. Preliminary study of the catalytic activity of the Ru complex for metathesis reactions demonstrated its inactive nature for the ring-closing metathesis (RCM), but an excellent thermo-switchability for the ring-opening metathesis polymerization of norbornene.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2021
Subjects:
электронный ресурс
труды учёных ТПУ
ruthenium catalyst
olefin metathesis-controlled initiation
2,5-disubstituted 1,3,4-oxadiazoles
ring-opening metathesis polymerization
latent catalysts
катализаторы
полимеризация
Online Access:https://doi.org/10.1016/j.tetlet.2021.153451
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=667892

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