An efficient and recyclable AgNO3/ionic liquid system catalyzed atmospheric CO2 utilization: Simultaneous synthesis of 2-oxazolidinones and α-hydroxyl ketones; Journal of Catalysis; Vol. 393

An efficient and recyclable AgNO3/ionic liquid system catalyzed atmospheric CO2 utilization: Simultaneous synthesis of 2-oxazolidinones and α-hydroxyl ketones; Journal of Catalysis; Vol. 393

Manylion Llyfryddiaeth
Parent link:	Journal of Catalysis Vol. 393.— 2021.— [P. 70-92]
Awdur Corfforaethol:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
Awduron Eraill:	Minchen Du, Gong Yanyan, Chao Bu, Jia Hu, Yongxing Zhang, Cheng Chen, Somboon Chaemchuen, Ye Yuan, Verpoort F. V. K. Frensis Valter Kornelius
Crynodeb:	Title screen Oxazolidinones and α-hydroxyl ketones are two series of fine chemicals that have been generally utilized in biological, pharmaceutical, and synthetic chemistry. Herein, a AgNO3/ionic liquid (IL) catalytic system was developed for the simultaneous synthesis of these compounds through the atom-economical three-component reactions of propargyl alcohols, 2-aminoethanols, and CO2. Notably, this system behaved excellent catalytic activity with the lowermost metal loading of 0.25 mol%. Meanwhile, it is the first reported metal-catalyzed system that could efficiently work under atmospheric CO2 pressure and be recycled at least five times. Evaluation of the green metrics proved the AgNO3/IL-catalyzed processes to be relatively more sustainable and greener than the other Ag-catalyzed examples. Further mechanistic investigations revealed the derivative active species of N-heterocyclic carbene (NHC) silver complexes and CO2 adducts generated during the process. Subsequently, their reactivity in this reaction was assessed for the first time, which was finally identified as beneficial for the catalytic activity. Режим доступа: по договору с организацией-держателем ресурса
Iaith:	Saesneg
Cyhoeddwyd:	2021
Pynciau:	электронный ресурс труды учёных ТПУ carbon dioxide utilization silver catalys multicomponent reaction heterocycles утилизация углекислый газ isionic liquid катализ ионные жидкости многокомпонентные реакции гетероциклы
Mynediad Ar-lein:	https://doi.org/10.1016/j.jcat.2020.11.011
Fformat:	Electronig Pennod Llyfr
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=667879

Eitemau Tebyg

Green Synthesis of 2-Oxazolidinones by an Efficient and Recyclable CuBr/Ionic Liquid System via CO2, Propargylic Alcohols, and 2-Aminoethanols; Catalysts; Vol. 11, iss. 2
Cyhoeddwyd: (2021)

CO2-induced dissolution of ZnO into ionic liquids and its catalytic application for the hydration of propargylic alcohols; Applied Catalysis B: Environmental; Vol. 310
Cyhoeddwyd: (2022)

The chemistry of heterocycles in the 21st century; Russian Chemical Reviews; Vol. 93, iss. 7
Cyhoeddwyd: (2024)

A green and recyclable CuSO4·5H2O/ionic liquid catalytic system for the CO2-promoted hydration of propargyl alcohols: an efficient assembly of α-hydroxy ketones; Journal of Catalysis; Vol. 405
Cyhoeddwyd: (2022)

Norton Utilities 8 для "чайников": пер. с англ.
gan: Слик Б. Бек
Cyhoeddwyd: (Киев, Диалектика, 1995)

Microexplosive Fragmentation of Liquid-Biofuel Droplets; Technical Physics Letters; Vol. 48, iss. 3
gan: Antonov D. V. Dmitry Vladimirovich
Cyhoeddwyd: (2022)

New reaction of terminal acetylenes with nitrates in the presence of sulfur trioxide: Heterocyclization into 3-acyl-5-aryl(alkyl)isoxazoles; Russian Journal of Organic Chemistry; Vol. 37, iss. 8
gan: Rogachev V. O. Victor Olegovich
Cyhoeddwyd: (2001)

Site Selective Concerted Nucleophilic Aromatic Substitutions of Azole-Ligated Diaryliodonium Salts; Advanced Synthesis and Catalysis; Vol. 365, iss. 4
Cyhoeddwyd: (2023)

Пакет Norton Utilities версии 5.0
Cyhoeddwyd: (Москва, И.В.К.-Софт, 1992)

A Green Procedure for the Diazotization-Iodination of Aromatic Amines under Aqueous, Strong-Acid-Free Conditions; Journal of Synthetic Organic Chemistry. Synthesis; 13
Cyhoeddwyd: (2011)

Heating, evaporation, fragmentation, and breakup of multi-component liquid droplets when heated in air flow; Chemical Engineering Research and Design; Vol. 146
gan: Antonov D. V. Dmitry Vladimirovich
Cyhoeddwyd: (2019)

Convenient Synthesis of Benziodazolone: New Reagents for Direct Esterification of Alcohols and Amidation of Amines; Molecules; Vol. 26, iss. 23
Cyhoeddwyd: (2021)

Кн. 5 : Norton Unilities 7.0. Ч. 1 : Общие сведения и Одиннадцать Самых Необходимых Полезняшек; Компьютер для носорога
Cyhoeddwyd: (1994)

Effect of high and low Nb content in multicomponent Nb–Ni–Ti–Zr–Co alloy on its structure, hardness and hydrogen permeability; Intermetallics; Vol. 166
Cyhoeddwyd: (2024)

Bis(benzotriazol-1-yl)methane as a linker in the assembly of new copper(II) coordination polymers: Synthesis, structure and investigations; Polyhedron; Vol. 48, iss. 1
Cyhoeddwyd: (2012)

Selective synthesis of a novel glycoluril-based hybrid compound with high application potential; Chemistry of Heterocyclic Compounds; Vol. 57, iss. 6
gan: Mamaeva E. A. Elena Andreevna
Cyhoeddwyd: (2021)

Features of the Synthesis of TiCAl (Fe2O3/TiO2) Metal Matrix Composites under Nonequilibrium Conditions; Energy Fluxes and Radiation Effects (EFRE-2020 online)
gan: Knyazeva A. G. Anna Georgievna
Cyhoeddwyd: (2020)

Закономерности изменений параметров процессов переноса многокомпонентных углеводородных газовых сред в условиях сепарации; Известия Томского политехнического университета [Известия ТПУ]. Инжиниринг георесурсов; Т. 330, № 10
gan: Николаев Е. В. Евгений Владимирович
Cyhoeddwyd: (2019)

Fundamental and applied aspects of the chemistry of acetylenylquinones; Resource-Efficient Technologies; No 4
gan: Vasilevsky S. F.
Cyhoeddwyd: (2019)

Efficient N-Heterocyclic Carbene/Ruthenium Catalytic Systems for the Alcohol Amidation with Amines: Involvement of Poly-Carbene Complexes?; ChemCatChem; Vol. 10, iss. 19
Cyhoeddwyd: (2018)

Exploration of nitrogen heterocycle scaffolds for the development of potent human neutrophil elastase inhibitors; Bioorganic & Medicinal Chemistry; Vol. 29, iss. 1
Cyhoeddwyd: (2021)

m-Iodosylbenzoic acid as a convenient recyclable hypervalent iodine oxidant for the synthesis of α-iodo ketones by oxidative iodination of ketones; Synthesis; № 21
Cyhoeddwyd: (2010)

Accumulation of isotope mixture components in a separation cascade; Journal of Engineering Physics and Thermophysics; Vol. 95 - № 2
gan: Ushakov A. A. Anton Andreevich
Cyhoeddwyd: (2022)

Theoretical Sensitivity Analysis of Fully Integrated Crude Fractionation Unit; Petroleum and Coal; Vol. 63, iss. 3
gan: Samborskaya M. A. Marina Anatolievna
Cyhoeddwyd: (2021)

Verdazyl Radical Building Blocks: Synthesis, Structure, and Sonogashira Cross-Coupling Reactions; European Journal of Organic Chemistry; Vol. 2018, iss. 34
Cyhoeddwyd: (2018)

Thermal Efficiency of Three-Cycle Utilization-Type Steam-Gas Units; Power Technology and Engineering; Vol. 48, iss. 6
gan: Galashov N. N. Nikolay Nikitovich
Cyhoeddwyd: (2015)

Facile Synthesis of 3-(Azol-1-yl)-1-adamantanecarboxylic Acids—New Bifunctional Angle-Shaped Building Blocks for Coordination Polymers; Molecules; Vol. 24, iss. 15
Cyhoeddwyd: (2019)

Synthesis of di(Imdazolium) and di(Pyrazolium) Salts as Precursors for N-heterocyclic Dicarbene Complexes; Procedia Chemistry; Vol. 10 : Chemistry and Chemical Engineering in XXI century
gan: Goncharova T. V.
Cyhoeddwyd: (2014)

Efficient Catalytic Synthesis of Condensed Isoxazole Derivatives via Intramolecular Oxidative Cycloaddition of Aldoximes; Molecules; Vol. 27, iss. 12
Cyhoeddwyd: (2022)

Modeling of nonstationary processes during separation of multicomponent isotope mixtures; Separation Science and Technology; Vol. 53, iss. 5
Cyhoeddwyd: (2018)

Исследование сепарационных процессов углеводородных многокомпонентных систем в режимах функционирования оборудования предварительной подготовки нефти; Известия Томского политехнического университета [Известия ТПУ]. Инжиниринг георесурсов; Т. 327, № 7
gan: Николаев Е. В. Евгений Владимирович
Cyhoeddwyd: (2016)

Thermal stability of N-heterocycle-stabilized iodanes – a systematic investigation; Beilstein Journal of Organic Chemistry; Vol. 15
Cyhoeddwyd: (2019)

Кн. 5 : Norton Unilities 7.0. Ч. 1 : Общие сведения и Одиннадцать Самых Необходимых Полезняшек; Компьютер для носорога
Cyhoeddwyd: (1995)

Review of technological progress in carbon dioxide capture, storage, and utilization; Gas Science and Engineering; Vol. 117
Cyhoeddwyd: (2023)

Математическое моделирование кинетики процесса плазменной утилизации отходов переработки ОЯТ в виде диспергированных горючих водно-органических композиций; Известия вузов. Физика; Т. 58, № 2, ч. 2
gan: Каренгин А. Г. Александр Григорьевич
Cyhoeddwyd: (2015)

Metal Embedded Porous Carbon for Efficient CO2 Cycloaddition under Mild Conditions; Catalysts; Vol. 12 iss. 4
Cyhoeddwyd: (2022)

The problems of utilizing graphite of stopped graphite-uranium reactors; Bulletin of the Tomsk Polytechnic University; Vol. 310, № 2
Cyhoeddwyd: (2007)

Особенности сепарации многокомпонентных углеводородных сред в режимах работы аппаратов подготовки нефти; Известия Томского политехнического университета [Известия ТПУ]. Инжиниринг георесурсов; Т. 329, № 3
gan: Николаев Е. В. Евгений Владимирович
Cyhoeddwyd: (2018)

Studying the utilization techniques of ammonium hexafluorosilicate; Bulletin of the Tomsk Polytechnic University; Vol. 311, № 3
Cyhoeddwyd: (2007)

Microstructure, Phase Composition, and Hydrogen Absorption in TiVCr Alloy Doped with Co, Ni, and Zr; Journal of Surface Investigation. X-ray, Synchrotron and Neutron Techniques; Vol. 19, iss. 4
Cyhoeddwyd: (2025)