Zefirov's reagent and related hypervalent iodine triflates; Mendeleev Communications; Vol. 31, iss. 3
| Parent link: | Mendeleev Communications Vol. 31, iss. 3.— 2021.— [P. 282-287] |
|---|---|
| Autor principal: | |
| Autor corporatiu: | |
| Altres autors: | |
| Sumari: | Title screen This minireview describes chemistry of hypervalent organoiodine triflates, which have received wide synthetic application as powerful electrophilic reagents and oxidants. The first representative of these compounds, µ-oxo-bis[(trifluoromethanesulfonato)(phenyl)iodine], was originally prepared and investigated in N. S. Zefirov's laboratory at Moscow State University in the early 1980s. This compound, now commonly known as Zefirov's reagent, is a useful reagent for the synthesis of various iodonium salts from the corresponding organic precursors. Recently, thermally stable and highly reactive triflates derived from cyclic hypervalent iodine compounds, benziodoxoles, have been reported and utilized in organic synthesis. The strongest iodine(V) oxidant, IBX-ditriflate, has been prepared from 2-iodoxybenzoic acid (IBX) and triflic acid. IBX-ditriflate can readily oxidize organic substrates that are generally resistant to oxidation. Режим доступа: по договору с организацией-держателем ресурса |
| Idioma: | anglès |
| Publicat: |
2021
|
| Matèries: | |
| Accés en línia: | https://doi.org/10.1016/j.mencom.2021.04.002 |
| Format: | MixedMaterials Electrònic Capítol de llibre |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=667811 |
Ítems similars
Benziodoxole-Derived Organosulfonates: The Strongest Hypervalent Iodine Electrophiles and Oxidants; Synlett; Vol. 31, № 4
Publicat: (2020)
Publicat: (2020)
Aryl-, Akynyl-, and Alkenylbenziodoxoles: Synthesis and Synthetic Applications; Molecules; Vol. 28, iss. 5
Publicat: (2023)
Publicat: (2023)
Iodonium ylides in organic synthesis; ARKIVOC; Vol. 2016
per: Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich)
Publicat: (2016)
per: Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich)
Publicat: (2016)
Preparation, structure, and reactivity of bicyclic benziodazole: a new hypervalent iodine heterocycle; Beilstein Journal of Organic Chemistry; Vol. 14
Publicat: (2018)
Publicat: (2018)
Hypervalent Iodine-Mediated Azidation Reactions; European Journal of Organic Chemistry; Vol. 2022, iss. 34
Publicat: (2022)
Publicat: (2022)
Iodonium Salts as Benzyne Precursors; Chemistry - A European Journal; Vol. 24, iss. 57
per: Yoshimura A. Akira
Publicat: (2018)
per: Yoshimura A. Akira
Publicat: (2018)
Preparation and X-ray structure of 2-iodoxybenzenesulfonicacid (IBS) – a powerful hypervalent iodine(V) oxidant; Beilstein Journal of Organic Chemistry; Vol. 14
Publicat: (2018)
Publicat: (2018)
Convenient Synthesis of Benziodazolone: New Reagents for Direct Esterification of Alcohols and Amidation of Amines; Molecules; Vol. 26, iss. 23
Publicat: (2021)
Publicat: (2021)
Application of hypervalent iodine compounds in advanced green technologies; Resource-Efficient Technologies; No 1
per: Zhdankin V. V.
Publicat: (2021)
per: Zhdankin V. V.
Publicat: (2021)
Hypervalent iodine in the structure of N-heterocycles: synthesis, structure, and application in organic synthesis; Chemistry of Heterocyclic Compounds; Vol. 56, iss. 7
Publicat: (2020)
Publicat: (2020)
Efficient Catalytic Synthesis of Condensed Isoxazole Derivatives via Intramolecular Oxidative Cycloaddition of Aldoximes; Molecules; Vol. 27, iss. 12
Publicat: (2022)
Publicat: (2022)
Preparation, Structure, and Reactivity of Pseudocyclic β-Trifluorosulfonyloxy Vinylbenziodoxolone Derivatives; Advanced Synthesis and Catalysis; Vol. 363, iss. 13
Publicat: (2021)
Publicat: (2021)
Synthesis of Oxazoline and Oxazole Derivatives by Hypervalent-Iodine-Mediated Oxidative Cycloaddition Reactions; Synthesis; Vol. 52, iss. 16
Publicat: (2020)
Publicat: (2020)
Generation of benzyne from aryl benziodoxaborole triflate under aqueous conditions and its reactions with alkyl aryl sulfides; Arkivoc; Vol. 1
Publicat: (2024)
Publicat: (2024)
Thermal stability of N-heterocycle-stabilized iodanes – a systematic investigation; Beilstein Journal of Organic Chemistry; Vol. 15
Publicat: (2019)
Publicat: (2019)
Synthesis of 2-fluorobenzoic acids by nucleophilic fluorination of 1-arylbenziodoxolones; Arkivoc; Vol. 2022, Part (vii) : Special Issue 'Hypervalent Iodine Chemistry, part 3
Publicat: (2022)
Publicat: (2022)
Site Selective Concerted Nucleophilic Aromatic Substitutions of Azole-Ligated Diaryliodonium Salts; Advanced Synthesis and Catalysis; Vol. 365, iss. 4
Publicat: (2023)
Publicat: (2023)
One-pot synthesis of diaryliodonium salts from arenes and aryl iodides with Oxone–sulfuric acid; Beilstein Journal of Organic Chemistry; Vol. 14
Publicat: (2018)
Publicat: (2018)
Imino‐λ3‐iodane and Catalytic Amount of I2‐Mediated Synthesis of N‐Allylsulfenamides via [2,3]‐Sigmatropic Rearrangement; European Journal of Organic Chemistry; Vol. 2020, iss. 41
Publicat: (2020)
Publicat: (2020)
Preparation, X-ray Structure, and Reactivity of Triisopropylsilyl-Substituted Aryliodonium Salts; European Journal of Organic Chemistry; Vol. 2015, iss. 22
Publicat: (2015)
Publicat: (2015)
Oxidative cycloaddition of hydroxamic acids with dienes or guaiacols mediated by iodine(III) reagents; Beilstein Journal of Organic Chemistry; Vol. 14
Publicat: (2018)
Publicat: (2018)
Halogen bonding in hypervalent halogen-based systems: Structural determinants and supramolecular diversity; Coordination Chemistry Reviews; Vol. 556
Publicat: (2026)
Publicat: (2026)
A New, Simple, and General Synthesis of N-Oxides of Iodopyridines and Iodoquinolines via the Diazotization–Iodination of Heterocyclic Amino N-Oxides in the Presence of p-Toluenesulfonic Acid in Water; Synthesis; Vol. 50, iss. 6
per: Krasnokutskaya E. A . Elena Aleksandrovna
Publicat: (2018)
per: Krasnokutskaya E. A . Elena Aleksandrovna
Publicat: (2018)
Influence of Residualizing Properties of the Radiolabel on Radionuclide Molecular Imaging of HER3 Using Affibody Molecules; International Journal of Molecular Sciences; Vol. 21, iss. 4
Publicat: (2020)
Publicat: (2020)
Benefit of Later-Time-Point PET Imaging of HER3 Expression Using Optimized Radiocobalt-Labeled Affibody Molecules; International Journal of Molecular Sciences; Vol. 21, iss. 6
Publicat: (2020)
Publicat: (2020)
Preparation and structure of phenolic aryliodonium salts; Chemical Communications; Vol. 54, iss. 73
Publicat: (2018)
Publicat: (2018)
Halogen Bonding Provides Heterooctameric Supramolecular Aggregation of Diaryliodonium Thiocyanate; Crystals; Vol. 10, iss. 3
Publicat: (2020)
Publicat: (2020)
Iodine Monoacetate for Efficient Oxyiodinations of Alkenes and Alkynes; Synlett; Vol. 29, iss. 4
Publicat: (2018)
Publicat: (2018)
Cyclotron Production of Iodine-124; Russian Physics Journal; Vol. 62, iss. 12
per: Salodkin S. S. Stepan Sergeevich
Publicat: (2020)
per: Salodkin S. S. Stepan Sergeevich
Publicat: (2020)
Investigation of preparative possibilities of iodinating systems on the basis of N-iodoacetamide; Bulletin of the Tomsk Polytechnic University; Vol. 311, № 3
Publicat: (2007)
Publicat: (2007)
DFT investigation of the thermodynamics and mechanism of electrophilic chlorination and iodination of arenes; Journal of Molecular Modeling; Vol. 17, iss. 11
Publicat: (2011)
Publicat: (2011)
Study of a surface of the potential energy for processes of alkanes free-radical iodination by B3LYP/DGDZVP method; Journal of Molecular Structure: Theochem; Vol. 912, iss. 1-3
Publicat: (2009)
Publicat: (2009)
2-Iodoxybenzoic acid ditriflate: the most powerful hypervalent iodine(v) oxidant; Chemical Communications; Vol. 55, iss. 54
Publicat: (2019)
Publicat: (2019)
Новые данные об элементном составе природных вод в районе распространения уровской (Кашина-Бека) болезни (Забайкальский край); Известия Томского политехнического университета [Известия ТПУ]. Инжиниринг георесурсов; Т. 330, № 1
Publicat: (2019)
Publicat: (2019)
Iodination and iodonitration of phenylacetylene under solvent-free conditions; Russian Journal of Organic Chemistry; Vol. 43, iss. 1
Publicat: (2007)
Publicat: (2007)
Iodination of aryl amines in a water-paste form via stable aryl diazonium tosylates; Tetrahedron Letters; Vol. 49, iss. 6
Publicat: (2008)
Publicat: (2008)
Potassium 4-Iodylbenzenesulfonate (PIBS) as a convenient water-soluble reagent based on hypervalent iodine; Химия и химическая технология в XXI веке; Т. 2
per: Mironova I. A. Irina Andreevna
Publicat: (2015)
per: Mironova I. A. Irina Andreevna
Publicat: (2015)
Synthesis of Radioiodinated Compounds. Classical Approaches and Achievements of Recent Years; International Journal of Molecular Sciences; Vol. 23, iss. 22
Publicat: (2022)
Publicat: (2022)
Определение повидон-иода в покрытиях имплантатов методом вольтамперометрии; Перспективы развития фундаментальных наук; Т. 2 : Химия
per: Левин Е. И.
Publicat: (2025)
per: Левин Е. И.
Publicat: (2025)
Preparation, structure, and oxidative reactivity of (dichloroiodo)pyridines: recyclable hypervalent iodine reagents; ARKIVOC; Vol. 2018, iss. part ii
Publicat: (2018)
Publicat: (2018)