Investigations into the Speciationof Inorganic Arsenicin Weakly Alkaline Medium by Voltammetry; Electroanalysis; Vol. 27, iss. 3

Investigations into the Speciationof Inorganic Arsenicin Weakly Alkaline Medium by Voltammetry; Electroanalysis; Vol. 27, iss. 3

Bibliographische Detailangaben
Parent link:Electroanalysis
Vol. 27, iss. 3.— 2015.— [P. 890–901]
Körperschaft: Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра гидрогеологии, инженерной геологии и гидрогеоэкологии (ГИГЭ)
Weitere Verfasser: Zakharova E. A. Elsa Arminana, Noskova G. N. Galina Nikolaevna, Moskaleva M. L. Marina Leonidovna, Elesova E. E. Elena Evgenjevna, Wildgoose G. G. Gregory
Zusammenfassung:Title screen
The speciation of inorganic forms of arsenic was studied using anodic stripping voltammetry (ASV) at a gold microelectrode in conjunction with photoreduction of As(V). Sodium sulfite (0.1 M) and ammonium buffer (pH≥9.5) were selected as both background electrolyte and photo-reductive reagent. Oxygen was removed by radical chain reactions with sulfite. The proposed speciation method was validated for mixtures of arsenic As(III/V) at concentrations up to 1 mg L−1. The calculated LOD of As(III/V) was 0.06 µg L−1 (3σ, tdep 40 s). Any interference from nitrate anions present at up to millimolar concentration was minimized by their photoreduction.
Режим доступа: по договору с организацией-держателем ресурса
Sprache:Englisch
Veröffentlicht: 2015
Schlagworte:
электронный ресурс
труды учёных ТПУ
мышьяк
вольтамперометрия
фотовосстановление
неорганические формы
Online-Zugang:https://doi.org/10.1002/elan.201500034
Format: Elektronisch Buchkapitel
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=667325

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