The effect of synthesis procedure on the catalytic performance of isostructural ZIF-8

The effect of synthesis procedure on the catalytic performance of isostructural ZIF-8

Bibliographic Details
Parent link:Applied Organometallic Chemistry
Vol. 32, iss. 2.— 2018.— [e4062, 6 p.]
Corporate Author: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
Other Authors: Mousavi B. Bibimaryam, Chaemchuen S. Somboon, Ezugwu C. I. Chizoba, Yuan Ye, Verpoort F. V. K. Frensis Valter Kornelius
Summary:Title screen
We demonstrate the synthesis of isostructural zeolitic imidazole framework (ZIF-8) using four distinct synthetic methods. Subsequently, the variations in physicochemical properties were analyzed through the catalytic reaction of CO2 cycloaddition of epoxide. It was thus demonstrated that simply by changing the type of synthetic method for the preparation of ZIF-8, the physicochemical properties were changed significantly which in turn influenced the catalytic activity of ZIF-8. It was found that the synthetic method affected the crystal growth and consequently influenced the physicochemical properties which are crucial aspects in metal–organic framework applications. There is an almost exponential relationship between the reactivity of various ZIF-8 samples in CO2 cycloaddition of epoxide and the surface area, CO2 adsorption and pore volume.
Language:English
Published: 2018
Subjects:
электронный ресурс
труды учёных ТПУ
Online Access:https://doi.org/10.1002/aoc.4062
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=667159

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