The effect of synthesis procedure on the catalytic performance of isostructural ZIF-8
| Parent link: | Applied Organometallic Chemistry Vol. 32, iss. 2.— 2018.— [e4062, 6 p.] |
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| مؤلف مشترك: | |
| مؤلفون آخرون: | , , , , |
| الملخص: | Title screen We demonstrate the synthesis of isostructural zeolitic imidazole framework (ZIF-8) using four distinct synthetic methods. Subsequently, the variations in physicochemical properties were analyzed through the catalytic reaction of CO2 cycloaddition of epoxide. It was thus demonstrated that simply by changing the type of synthetic method for the preparation of ZIF-8, the physicochemical properties were changed significantly which in turn influenced the catalytic activity of ZIF-8. It was found that the synthetic method affected the crystal growth and consequently influenced the physicochemical properties which are crucial aspects in metal–organic framework applications. There is an almost exponential relationship between the reactivity of various ZIF-8 samples in CO2 cycloaddition of epoxide and the surface area, CO2 adsorption and pore volume. |
| اللغة: | الإنجليزية |
| منشور في: |
2018
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| الموضوعات: | |
| الوصول للمادة أونلاين: | https://doi.org/10.1002/aoc.4062 |
| التنسيق: | الكتروني فصل الكتاب |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=667159 |
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| 200 | 1 | |a The effect of synthesis procedure on the catalytic performance of isostructural ZIF-8 |f B. Mousavi, S. Chaemchuen, C. I. Ezugwu [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 27 tit.] | ||
| 330 | |a We demonstrate the synthesis of isostructural zeolitic imidazole framework (ZIF-8) using four distinct synthetic methods. Subsequently, the variations in physicochemical properties were analyzed through the catalytic reaction of CO2 cycloaddition of epoxide. It was thus demonstrated that simply by changing the type of synthetic method for the preparation of ZIF-8, the physicochemical properties were changed significantly which in turn influenced the catalytic activity of ZIF-8. It was found that the synthetic method affected the crystal growth and consequently influenced the physicochemical properties which are crucial aspects in metal–organic framework applications. There is an almost exponential relationship between the reactivity of various ZIF-8 samples in CO2 cycloaddition of epoxide and the surface area, CO2 adsorption and pore volume. | ||
| 461 | |t Applied Organometallic Chemistry | ||
| 463 | |t Vol. 32, iss. 2 |v [e4062, 6 p.] |d 2018 | ||
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| 701 | 1 | |a Chaemchuen |b S. |g Somboon | |
| 701 | 1 | |a Ezugwu |b C. I. |g Chizoba | |
| 701 | 0 | |a Yuan Ye | |
| 701 | 1 | |a Verpoort |b F. V. K. |c Chemical Engineer |c Professor of Tomsk Polytechnic University, doctor of chemical Sciences |f 1963- |g Frensis Valter Kornelius |3 (RuTPU)RU\TPU\pers\35059 |9 18334 | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Исследовательская школа химических и биомедицинских технологий |c (2017- ) |3 (RuTPU)RU\TPU\col\23537 |
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