Reversible switching of PEDOT:PSS conductivity in the dielectric-conductive range through the redistribution of light-governing polymers; RSC Advances; Vol. 8, iss. 20

Reversible switching of PEDOT:PSS conductivity in the dielectric-conductive range through the redistribution of light-governing polymers; RSC Advances; Vol. 8, iss. 20

書目詳細資料
Parent link:	RSC Advances Vol. 8, iss. 20.— 2018.— [P. 11198-11206]
企業作者:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
其他作者:	Kalachyova E. Evgeniya, Guselnikova O. A. Olga Andreevna, Postnikov P. S. Pavel Sergeevich, Fitl P. Petr, Lapchak L. Leo, Svorcik V. Vaclav, Lyutakov O. Oleksy
總結:	Title screen One of the biggest challenges in the field of organic electronics is the creation of flexible, stretchable, and biofavorable materials. Here the simple and repeatable method for reversible writing/erasing of arbitrary conductive pattern in conductive polymer thin film is proposed. The copolymer azo-modified poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) was synthesized to achieve reversible photo-induced local electrical switching in the insulator-semimetal range. The photoisomerization of the polymer was induced by grafting nitrobenzenediazonium tosylate to the PSS main chains. While the as-deposited PEDOT:PSS thin films showed good conductivity, the modification procedure generated polymer redistribution, resulting in an island-like PEDOT distribution and the loss of conductivity. Further local illumination (430 nm) led to the azo-isomerization redistribution of the polymer chains and the creation of a conductive pattern in the insulating polymer film. The created pattern could then be erased by illumination at a second wavelength (470 nm), which was attributed to induction of reverse azo-isomerization. In this way, the reversible writing/erasing of arbitrary conductive patterns in thin polymer films was realized. Режим доступа: по договору с организацией-держателем ресурса
語言:	英语
出版:	2018
主題:	электронный ресурс труды учёных ТПУ диэлектрическая проводимость полимерные пленки осаждение
在線閱讀:	https://doi.org/10.1039/C7RA12624G
格式:	電子 Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=667134

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