Preparation of Zr(Mo, W)2O8 with a larger negative thermal expansion by controlling the thermal decomposition of Zr(Mo, W)2(OH, Cl)2∙2H2O; Scientific Reports; Vol. 8

Preparation of Zr(Mo, W)2O8 with a larger negative thermal expansion by controlling the thermal decomposition of Zr(Mo, W)2(OH, Cl)2∙2H2O; Scientific Reports; Vol. 8

Dettagli Bibliografici
Parent link:Scientific Reports
Vol. 8.— 2018.— [5337, 7 p.]
Ente Autore: Национальный исследовательский Томский политехнический университет Инженерная школа новых производственных технологий Отделение материаловедения
Altri autori: Petrushina M. Yu. Mariya Yurjevna, Dedova E. S. Elena Sergeevna, Filatov E. Yu. Evgeny Yurjevich, Plyusnin P. E. Pavel Evgenjevich, Korenev S. V. Sergey Vasiljevich, Kulkov S. N. Sergey Nikolaevich, Derevyannikova E. A. Elizaveta, Sharafutdinov M. R. Marat, Gubanov A. I. Aleksandr Iridievich
Riassunto:Title screen
Solid solutions of Zr(Mo,W)2O7(OH,Cl)2∙2H2O with a preset ratio of components were prepared by a hydrothermal method. The chemical composition of the solutions was determined by energy dispersive X-ray spectroscopy (EDX). For all the samples of ZrMoxW2−xO7(OH,Cl)2∙2H2O (x = 0.0, 0.2, 0.4, 0.6, 0.8, 1.0, 1.2, 1.4, 1.6, 1.8, and 2.0), TGA and in situ powder X-ray diffraction (PXRD) studies (300-1100 K) were conducted. For each case, the boundaries of the transformations were determined: Zr(Mo,W)2O7(OH,Cl)2∙2H2O → orthorhombic-ZrMoxW2−xO8 (425-525 K), orthorhombic-ZrMoxW2−xO8 → cubic-ZrMoxW2−xO8 (700-850 K), cubic-ZrMoxW2−xO8 → trigonal-ZrMoxW2−xO8 (800-1050 K for x > 1) and cubic-ZrMoxW2−xO8 → oxides (1000-1075 K for x ≤ 1). The cell parameters of the disordered cubic-ZrMoxW2−xO8 (space group Pa-3) were measured within 300-900 K, and the thermal expansion coefficients were calculated: −3.5∙10−6 - −4.5∙10−6 K−1. For the ordered ZrMo1.8W0.2O8 (space group P213), a negative thermal expansion (NTE) coefficient −9.6∙10−6 K−1 (300-400 K) was calculated. Orthorhombic-ZrW2O8 is formed upon the decomposition of ZrW2O7(OH,Cl)2∙2H2O within 500-800 K.
Lingua:inglese
Pubblicazione: 2018
Soggetti:
электронный ресурс
труды учёных ТПУ
тепловое расширение
термическое разложение
твердые растворы
химический состав
Accesso online:https://doi.org/10.1038/s41598-018-23529-6
Natura: xMaterials Elettronico Capitolo di libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=667037

Documenti analoghi

Documenti analoghi