Synthesis and study of Pd-Rh alloy nanoparticles and alumina-supported low-content Pd-Rh catalysts for CO oxidation; Materials Research Bulletin; Vol. 102

Synthesis and study of Pd-Rh alloy nanoparticles and alumina-supported low-content Pd-Rh catalysts for CO oxidation; Materials Research Bulletin; Vol. 102

מידע ביבליוגרפי
Parent link:Materials Research Bulletin
Vol. 102.— 2018.— [P. 196-202]
Corporate Authors: Национальный исследовательский Томский политехнический университет Инженерная школа энергетики Научно-образовательный центр И. Н. Бутакова (НОЦ И. Н. Бутакова), Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
מחברים אחרים: Vedyagin A. A. Aleksey Anatolievich, Plyusnin P. E. Pavel Evgenjevich, Rybinskaya А. А., Shubin Yu. V. Yury Viktorovich, Mishakov I. V. Iljya Vladimirovich, Korenev S. V. Sergey Vasiljevich
סיכום:Title screen
Palladium and rhodium are known to be partly miscible metals. In present work, the peculiarities of coordination compound [Pd(NH3)4]3[Rh(NO2)6]2 decomposition with formation of nanosized solid solutions under different atmospheres were studied by means of thermal gravimetry. Formation of alloy nanoparticles were confirmed by powder X-ray diffraction analysis, scanning and transmission electron microscopies. A bimetallic Pd-Rh/alumina catalyst was prepared by incipient wetness impregnation using coordination compound [Pd(NH3)4]3[Rh(NO2)6]2 as a precursor. Monometallic reference samples were obtained using [Pd(NH3)4](NO3)2 and Na3[Rh(NO2)6], correspondingly. Catalytic performance and stability of the catalysts were examined in a model reaction of CO oxidation in a prompt thermal aging regime. The environment of precursor decomposition was shown to affect noticeably both the initial activity and stability of the samples in the studied reaction. Reductive atmosphere in comparison with inert and oxidative ones facilitates the formation of the smallest active component species, which demonstrate highest initial activity but worst stability.
Режим доступа: по договору с организацией-держателем ресурса
שפה:אנגלית
יצא לאור: 2018
נושאים:
электронный ресурс
труды учёных ТПУ
partly miscible metals
palladium-rhodium alloy
CO oxidation
catalyst preparation conditions
double complex salts
сплавы
металлы
окисление
катализаторы
комплексные соли
גישה מקוונת:https://doi.org/10.1016/j.materresbull.2018.02.038
פורמט: אלקטרוני Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=666703

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