Synthesis of carbon nanofibers by catalytic CVD of chlorobenzene over bulk nickel alloy; Applied Surface Science; Vol. 427, Pt. B
| Parent link: | Applied Surface Science Vol. 427, Pt. B.— 2018.— [P. 505-510] |
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| مؤلفون مشاركون: | , |
| مؤلفون آخرون: | , , , , |
| الملخص: | Title screen Catalytic chemical vapor deposition (CCVD) of chlorobenzene over bulk nickel alloy (nichrome) was studied. The bulk Ni-containing samples being exposed to a contact with aggressive reaction medium undergo self-disintegration followed by growth of carbon nanofibers. This process, also known as a metal dusting, requires the simultaneous presence of chlorine and hydrogen sources in the reaction mixture. Molecule of chlorobenzene complies with these requirements. The experiments on CCVD were performed in a flow-through reactor system. The initial stages of nickel disintegration process were investigated in a closed system under Autogenic Pressure at Elevated Temperature (RAPET) conditions. Scanning and transmission electron microscopies and ferromagnetic resonance spectroscopy were applied to examine the samples after their interaction with chlorobenzene. Introduction of additional hydrogen into the flow-through system was shown to affect the morphology of grown carbon nanofibers. Режим доступа: по договору с организацией-держателем ресурса |
| اللغة: | الإنجليزية |
| منشور في: |
2018
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| الموضوعات: | |
| الوصول للمادة أونلاين: | https://doi.org/10.1016/j.apsusc.2017.08.227 |
| التنسيق: | الكتروني فصل الكتاب |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=666701 |
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| 200 | 1 | |a Synthesis of carbon nanofibers by catalytic CVD of chlorobenzene over bulk nickel alloy |f R. Kenzhin, Yu. I. Bauman, A. M. Volodin [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 36 tit.] | ||
| 330 | |a Catalytic chemical vapor deposition (CCVD) of chlorobenzene over bulk nickel alloy (nichrome) was studied. The bulk Ni-containing samples being exposed to a contact with aggressive reaction medium undergo self-disintegration followed by growth of carbon nanofibers. This process, also known as a metal dusting, requires the simultaneous presence of chlorine and hydrogen sources in the reaction mixture. Molecule of chlorobenzene complies with these requirements. The experiments on CCVD were performed in a flow-through reactor system. The initial stages of nickel disintegration process were investigated in a closed system under Autogenic Pressure at Elevated Temperature (RAPET) conditions. Scanning and transmission electron microscopies and ferromagnetic resonance spectroscopy were applied to examine the samples after their interaction with chlorobenzene. Introduction of additional hydrogen into the flow-through system was shown to affect the morphology of grown carbon nanofibers. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Applied Surface Science | ||
| 463 | |t Vol. 427, Pt. B |v [P. 505-510] |d 2018 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a self-disintegration | |
| 610 | 1 | |a bulk nickel alloy | |
| 610 | 1 | |a chlorobenzene | |
| 610 | 1 | |a CCVD | |
| 610 | 1 | |a RAPET conditions | |
| 610 | 1 | |a ferromagnetic resonance | |
| 610 | 1 | |a никелевые сплавы | |
| 610 | 1 | |a хлорбензол | |
| 610 | 1 | |a ферромагнитный резонанс | |
| 701 | 1 | |a Kenzhin |b R. |g Roman | |
| 701 | 1 | |a Bauman |b Yu. I. |g Yury | |
| 701 | 1 | |a Volodin |b A. M. |g Aleksandr | |
| 701 | 1 | |a Mishakov |b I. V. |c chemist |c Associate Professor of Tomsk Polytechnic University, candidate of chemical sciences |f 1977- |g Iljya Vladimirovich |3 (RuTPU)RU\TPU\pers\36375 | |
| 701 | 1 | |a Vedyagin |b A. A. |c Chemist |c Chief Expert of Tomsk Polytechnic University, Candidate of chemical sciences |f 1975- |g Aleksey Anatolievich |3 (RuTPU)RU\TPU\pers\36694 | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Инженерная школа энергетики |b Научно-образовательный центр И. Н. Бутакова (НОЦ И. Н. Бутакова) |3 (RuTPU)RU\TPU\col\23504 |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Исследовательская школа химических и биомедицинских технологий |c (2017- ) |3 (RuTPU)RU\TPU\col\23537 |
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| 856 | 4 | |u https://doi.org/10.1016/j.apsusc.2017.08.227 | |
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