The role of chemisorbed water in formation and stabilization of active sites on Pd/Alumina oxidation catalysts; Catalysis Today; Vol. 307

The role of chemisorbed water in formation and stabilization of active sites on Pd/Alumina oxidation catalysts; Catalysis Today; Vol. 307

Detaylı Bibliyografya
Parent link:	Catalysis Today Vol. 307.— 2018.— [P. 102-110]
Kurumsal yazarlar:	Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий, Национальный исследовательский Томский политехнический университет Инженерная школа энергетики Научно-образовательный центр И. Н. Бутакова (НОЦ И. Н. Бутакова)
Diğer Yazarlar:	Vedyagin A. A. Aleksey Anatolievich, Volodin A. M. Aleksandr, Kenzhin R. M. Roman, Stoyanovskii V. O. Vladimir, Rogov V. A. Vladimir, Kriventsov V. V. Vladimir Vladimirovich, Mishakov I. V. Iljya Vladimirovich
Özet:	Title screen A series of Pd/Al2O3 catalysts with different palladium loading was prepared by incipient wetness impregnation method. As it was shown by various physicochemical methods, palladium at concentrations not exceeding 0.5 wt.% favors to stabilize in an atomic dispersed ionic state. Appearance of PdO phase has been firmly detected by TPR, DR UV-vis and EXAFS starting from Pd concentration of 1 wt.%. It was found that low-content Pd/Al2O3 catalysts are characterized by high activity in CO oxidation due to atomically dispersed palladium species tailored to the donor sites of the support. The presence of chemisorbed water allows one to stabilize Pd in highly disperse state thus preventing the catalyst deactivation. Режим доступа: по договору с организацией-держателем ресурса
Dil:	İngilizce
Baskı/Yayın Bilgisi:	2018
Konular:	электронный ресурс труды учёных ТПУ CO oxidation palladium catalysts alumina stability chemisorbed water окисление палладиевые катализаторы глиноземы воды
Online Erişim:	https://doi.org/10.1016/j.cattod.2017.01.033
Materyal Türü:	Elektronik Kitap Bölümü
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=666656

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