One-step production of 3D printed ferroelectric polymer forms using fused deposition modeling; Applied Physics Letters; Vol. 119, iss. 20

One-step production of 3D printed ferroelectric polymer forms using fused deposition modeling; Applied Physics Letters; Vol. 119, iss. 20

Bibliographische Detailangaben
Parent link:Applied Physics Letters
Vol. 119, iss. 20.— 2021.— [202902, 12 p.]
Körperschaften: Национальный исследовательский Томский политехнический университет Инженерная школа ядерных технологий Научно-образовательный центр Б. П. Вейнберга, Национальный исследовательский Томский политехнический университет Инженерная школа ядерных технологий Лаборатория плазменных гибридных систем
Weitere Verfasser: Akimchenko I. O. Igor Olegovich, Dubinenko G. E. Gleb Evgenjevich, Rutkowski S. Sven, Vorobjev A. O. Aleksandr Olegovich, Buznik V. M. Vyacheslav Mikhaylovich, Bolbasov E. N. Evgeny Nikolaevich
Zusammenfassung:Title screen
This Letter presents the possibility of 3D print polymer forms with a ferroelectric crystal structure in a one-step process by using the fused deposition modeling method. The approach does not require any additional equipment, other than an extruder for filament production and a commercial 3D printer to fabricate ferroelectric polymer forms. By using the copolymer of vinylidene fluoride and tetrafluoroethylene as a filament for 3D printing, complex spatial structures, such as the gyroid form, are accessible. Compared to polyvinylidene fluoride, the copolymer of vinylidene fluoride and tetrafluoroethylene retains its ferroelectric properties even after melting in the 3D printing process and soldification. The x-ray diffraction investigation shows that the 3D forms are having a planar zigzag conformation on macromolecule scales, which relates to a crystal structure with ferroelectric properties. Annealing the 3D forms at a temperature of 110 C for 12 h does not cause any changes to the spatial polymer structures but leads to an increase in the degree of crystallinity by more than 20%. This result contributes to an increase in the ferroelectric crystalline phase content by 17% and the Curie temperature by 7 C in contrast to non-annealed 3D forms.
AM_Agreement
Sprache:Englisch
Veröffentlicht: 2021
Schlagworte:
электронный ресурс
труды учёных ТПУ
3D-печать
полимеры
наплавление
сополимеры
дифракция
рентгеновские лучи
Online-Zugang:https://doi.org/10.1063/5.0070365
Format: Elektronisch Buchkapitel
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=666373

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