Thermal Analysis of Processes at the Solid-Phase Synthesis of Lithium-Titanium Ferrite; Russian Journal of Physical Chemistry A; Vol. 95, iss. 5

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Parent link:Russian Journal of Physical Chemistry A
Vol. 95, iss. 5.— 2021.— [P. 882-886]
Hlavní autor: Nikolaev E. V. Evgeny Vladimirovich
Korporativní autor: Национальный исследовательский Томский политехнический университет Институт неразрушающего контроля Проблемная научно-исследовательская лаборатория электроники, диэлектриков и полупроводников
Další autoři: Lysenko E. N. Elena Nikolaevna, Surzhikov A. P. Anatoly Petrovich
Shrnutí:Title screen
In this study, the reactivity of a Fe2O3–Li2CO3–TiO2 mixture with different initial densities was investigated by thermal and kinetic methods to analyze phase formation of lithium titanium ferrite. Test samples were powder with a density of 1 g/cm3 and a compact with a density of 2.6 g/cm3. High-density samples were formed by single-action cold compaction. It is shown that the reaction of solid-phase interaction of lithium-titanium ferrite strongly depends on the degree of compaction. The mass of the powder mixture sample decreases in the temperature range of 500–720°C. In compacts, the reaction of solid-phase interaction starts at lower temperature (~420°C). In addition, it is shown that in compacted samples, a lithium ferrite spinel phase is formed during heating. The kinetic analysis was used to determine the kinetic model of the synthesis reaction of lithium-titanium ferrite and to calculate the parameters of this process.
Режим доступа: по договору с организацией-держателем ресурса
Jazyk:angličtina
Vydáno: 2021
Témata:
On-line přístup:https://doi.org/10.1134/S0036024421050204
Médium: MixedMaterials Elektronický zdroj Kapitola
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=666099

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200 1 |a Thermal Analysis of Processes at the Solid-Phase Synthesis of Lithium-Titanium Ferrite  |f E. V. Nikolaev, E. N. Lysenko, A. P. Surzhikov 
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330 |a In this study, the reactivity of a Fe2O3–Li2CO3–TiO2 mixture with different initial densities was investigated by thermal and kinetic methods to analyze phase formation of lithium titanium ferrite. Test samples were powder with a density of 1 g/cm3 and a compact with a density of 2.6 g/cm3. High-density samples were formed by single-action cold compaction. It is shown that the reaction of solid-phase interaction of lithium-titanium ferrite strongly depends on the degree of compaction. The mass of the powder mixture sample decreases in the temperature range of 500–720°C. In compacts, the reaction of solid-phase interaction starts at lower temperature (~420°C). In addition, it is shown that in compacted samples, a lithium ferrite spinel phase is formed during heating. The kinetic analysis was used to determine the kinetic model of the synthesis reaction of lithium-titanium ferrite and to calculate the parameters of this process. 
333 |a Режим доступа: по договору с организацией-держателем ресурса 
461 |t Russian Journal of Physical Chemistry A 
463 |t Vol. 95, iss. 5  |v [P. 882-886]  |d 2021 
610 1 |a электронный ресурс 
610 1 |a труды учёных ТПУ 
610 1 |a lithium-titanium ferrite 
610 1 |a solid-phase synthesis 
610 1 |a thermal analysis 
610 1 |a kinetic analysis 
610 1 |a литий-титановые ферриты 
610 1 |a твердофазный синтез 
610 1 |a термический анализ 
610 1 |a кинетический анализ 
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701 1 |a Lysenko  |b E. N.  |c Specialist in the field of electrical engineering  |c Professor of Tomsk Polytechnic University, Doctor of technical sciences  |f 1972-  |g Elena Nikolaevna  |3 (RuTPU)RU\TPU\pers\32050  |9 16097 
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