Synthesis, Crystal Structure, and Luminescent Properties of Novel Zinc Metal-Organic Frameworks Based on 1,3-Bis(1,2,4-triazol-1-yl)propane; Crystal Growth & Design; Vol. 17, iss. 10

Bibliographische Detailangaben
Parent link:Crystal Growth & Design
Vol. 17, iss. 10.— 2017.— [Р. 5559-5567]
Körperschaft: Национальный исследовательский Томский политехнический университет Инженерная школа энергетики Отделение электроэнергетики и электротехники
Weitere Verfasser: Semitut E. Yu. Evgeny Yurjevich, Sukhikh T. S. Taisiya Sergeevna, Filatov E. Yu. Evgeny Yurjevich, Anosova G. A. Galina Aleksandrovna, Ryadun A. A. Alexey Andreevich, Kovalenko K. A. Konstantin Aleksandrovich, Potapov A. S. Andrey Sergeevich
Zusammenfassung:Title screen
Three new zinc three-dimensional coordination polymers with flexible 1,3-bis(1,2,4-triazol-1-yl)propane ligand were synthesized. The crystal structures of synthesized compounds were determined, and structural peculiarities are discussed. Coordination compounds with composition [Zn(btrp)(bdc)]·nDMF are interpenetrated frameworks, while metal-organic framework (MOF) [Zn3(btrp)(bdc)3]·nDMF is not. Thermal stability and luminescent properties of synthesized compounds have been investigated. The possibility of usage of such compounds as sensitive materials for some aromatic compounds are explored, and it was shown that luminescence of coordination polymers is completely quenched in the presence of nitrobenzene. Sorption properties of synthesized MOFs toward nitrogen, carbon dioxide, and hydrogen were evaluated.
Sprache:Englisch
Veröffentlicht: 2017
Schlagworte:
Online-Zugang:https://doi.org/10.1021/acs.cgd.7b01133
Format: MixedMaterials Elektronisch Buchkapitel
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=665857

MARC

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200 1 |a Synthesis, Crystal Structure, and Luminescent Properties of Novel Zinc Metal-Organic Frameworks Based on 1,3-Bis(1,2,4-triazol-1-yl)propane  |f E. Yu. Semitut, T. S. Sukhikh, E. Yu. Filatov [et al.] 
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330 |a Three new zinc three-dimensional coordination polymers with flexible 1,3-bis(1,2,4-triazol-1-yl)propane ligand were synthesized. The crystal structures of synthesized compounds were determined, and structural peculiarities are discussed. Coordination compounds with composition [Zn(btrp)(bdc)]·nDMF are interpenetrated frameworks, while metal-organic framework (MOF) [Zn3(btrp)(bdc)3]·nDMF is not. Thermal stability and luminescent properties of synthesized compounds have been investigated. The possibility of usage of such compounds as sensitive materials for some aromatic compounds are explored, and it was shown that luminescence of coordination polymers is completely quenched in the presence of nitrobenzene. Sorption properties of synthesized MOFs toward nitrogen, carbon dioxide, and hydrogen were evaluated. 
461 |t Crystal Growth & Design 
463 |t Vol. 17, iss. 10  |v [Р. 5559-5567]  |d 2017 
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701 1 |a Semitut  |b E. Yu.  |g Evgeny Yurjevich 
701 1 |a Sukhikh  |b T. S.  |g Taisiya Sergeevna 
701 1 |a Filatov  |b E. Yu.  |g Evgeny Yurjevich 
701 1 |a Anosova  |b G. A.  |g Galina Aleksandrovna 
701 1 |a Ryadun  |b A. A.  |g Alexey Andreevich 
701 1 |a Kovalenko  |b K. A.  |g Konstantin Aleksandrovich 
701 1 |a Potapov  |b A. S.  |c Chemist  |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences  |f 1981-  |g Andrey Sergeevich  |3 (RuTPU)RU\TPU\pers\33909 
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