The Simultaneous Voltammetric Determination of Aflatoxins В1 and М1 on a Glassy-Carbon Electrode; Journal of Analytical Methods in Chemistry; Vol. 2018
| Источник: | Journal of Analytical Methods in Chemistry Vol. 2018.— 2018.— [6285623, 6 p.] |
|---|---|
| Корпоративные авторы: | , |
| Другие авторы: | , , , |
| Примечания: | Title screen For the first time, the possibility of using stripping voltammetry for the simultaneous determination of aflatoxins C1 and N1 on a glassy-carbon electrode has been shown. +e influence of various factors (F[upsilon], [tau][upsilon], w, and the nature of the background electrolyte) on the potential and magnitude of the oxidation current of mycotoxins has been estimated. Working conditions for voltammetric determination and reproducibility of analytical signals for two mycotoxins have been selected. +e mutual influence of aflatoxins C1 and N1 on the value of analytical signals in their simultaneous presence has been studied. It has been found that, in the range of their detectable contents, the presence of aflatoxin C1 reduces the analytical signal of aflatoxin N1 by 45-50%, but the linearity of the calibration dependence is preserved. +e content of aflatoxin N1 in determination of aflatoxin B1 does not exert a significant effect in the range of 10-15%. Based on the results obtained, a procedure has been proposed for determining the content of aflatoxins C1 and N1 in their joint presence in milk by voltammetry in the concentration ranges 2•10-3-:2•101 mg/dm3 and 2•10-4-:2•102 mg/dm3 , respectively (Sr not more than 18%). |
| Язык: | английский |
| Опубликовано: |
2018
|
| Предметы: | |
| Online-ссылка: | https://doi.org/10.1155/2018/6285623 |
| Формат: | Электронный ресурс Статья |
| Запись в KOHA: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=665405 |
MARC
| LEADER | 00000naa0a2200000 4500 | ||
|---|---|---|---|
| 001 | 665405 | ||
| 005 | 20250203154036.0 | ||
| 035 | |a (RuTPU)RU\TPU\network\36604 | ||
| 035 | |a RU\TPU\network\28947 | ||
| 090 | |a 665405 | ||
| 100 | |a 20210922d2018 k||y0rusy50 ba | ||
| 101 | 0 | |a eng | |
| 102 | |a US | ||
| 135 | |a drcn ---uucaa | ||
| 181 | 0 | |a i | |
| 182 | 0 | |a b | |
| 200 | 1 | |a The Simultaneous Voltammetric Determination of Aflatoxins В1 and М1 on a Glassy-Carbon Electrode |f G. B. Slepchenko, T. M. Gindullina, M. A. Gavrilova, A. Zh. Auelbekova | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 24 tit.] | ||
| 330 | |a For the first time, the possibility of using stripping voltammetry for the simultaneous determination of aflatoxins C1 and N1 on a glassy-carbon electrode has been shown. +e influence of various factors (F[upsilon], [tau][upsilon], w, and the nature of the background electrolyte) on the potential and magnitude of the oxidation current of mycotoxins has been estimated. Working conditions for voltammetric determination and reproducibility of analytical signals for two mycotoxins have been selected. +e mutual influence of aflatoxins C1 and N1 on the value of analytical signals in their simultaneous presence has been studied. It has been found that, in the range of their detectable contents, the presence of aflatoxin C1 reduces the analytical signal of aflatoxin N1 by 45-50%, but the linearity of the calibration dependence is preserved. +e content of aflatoxin N1 in determination of aflatoxin B1 does not exert a significant effect in the range of 10-15%. Based on the results obtained, a procedure has been proposed for determining the content of aflatoxins C1 and N1 in their joint presence in milk by voltammetry in the concentration ranges 2•10-3-:2•101 mg/dm3 and 2•10-4-:2•102 mg/dm3 , respectively (Sr not more than 18%). | ||
| 461 | |t Journal of Analytical Methods in Chemistry | ||
| 463 | |t Vol. 2018 |v [6285623, 6 p.] |d 2018 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a вольтамперометрическое определение | |
| 610 | 1 | |a афлатоксины | |
| 610 | 1 | |a стеклоуглеродные электроды | |
| 610 | 1 | |a вольтамперометрия | |
| 701 | 1 | |a Slepchenko |b G. B. |c Chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1956- |g Galina Borisovna |3 (RuTPU)RU\TPU\pers\33018 |9 16858 | |
| 701 | 1 | |a Gindullina |b T. M. |c Chemist |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences |f 1951- |g Tatiana Mikhailovna |3 (RuTPU)RU\TPU\pers\33021 | |
| 701 | 1 | |a Gavrilova |b M. A. |g Mariya | |
| 701 | 1 | |a Auelbekova |b A. Zh. | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Исследовательская школа химических и биомедицинских технологий |c (2017- ) |3 (RuTPU)RU\TPU\col\23537 |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Инженерная школа природных ресурсов |b Отделение химической инженерии |3 (RuTPU)RU\TPU\col\23513 |
| 801 | 2 | |a RU |b 63413507 |c 20210922 |g RCR | |
| 856 | 4 | |u https://doi.org/10.1155/2018/6285623 | |
| 942 | |c CF | ||