First high resolution study of the pentad bending bands of deuterated silane: Energy structure of the (0200), (0101) and (0002) vibrational states of 28SiD4, 29SiD4 and 30SiD4

First high resolution study of the pentad bending bands of deuterated silane: Energy structure of the (0200), (0101) and (0002) vibrational states of 28SiD4, 29SiD4 and 30SiD4

Bibliographic Details
Parent link:	Journal of Quantitative Spectroscopy and Radiative Transfer Vol. 273.— 2021.— [107856, 13 p.]
Corporate Author:	Национальный исследовательский Томский политехнический университет Исследовательская школа физики высокоэнергетических процессов
Other Authors:	Ulenekov (Ulenikov) O. N. Oleg Nikolaevich, Gromova O. V. Olga Vasilievna, Bekhtereva E. S. Elena Sergeevna, Raspopova N. I. Natalya Ivanovna, Kuznetsov A. V. Aleksey Valerjevich, Leroy C. A. Claude, Sydow Ch. Christian, Bauerekker Z. Zigurd
Summary:	Title screen The infrared spectra of SiD in natural abundance were measured in the region of 350-2050 cm{-1} with a Bruker IFS 125HR Fourier transform interferometer at an optical resolution of 0.0021 and 0.0016 cm{-1} and analyzed. Not less than 6490 transitions with Jmax=33 were assigned for the first time to the bands and of the SiD molecule. Numerous “hot” dyad-pentad transitions (in general, 5545 “hot” transitions) were also assigned for the first time in the region of 600-760 cm. Rotational, centrifugal distortion, tetrahedral splitting, and interaction parameters for the and vibrational states were determined from the fit of experimental line positions. The obtained set of 69 fitted parameters reproduces the initial experimental data with an accuracy of for the 6490 “cold” transitions and for the 5545 “hot” transitions. Results of the analogues analysis for the SiD and SiD isotopologues with 403/136 “cold” and 171/99 “hot” assigned transitions are presented also. Режим доступа: по договору с организацией-держателем ресурса
Published:	2021
Subjects:	электронный ресурс труды учёных ТПУ 2v2 2v4 v2+v4 bands of 28SiD4 29SiD4 30SiD4"hot" Pentad-Dyad transitions of 28SiD4 30SiD4Line positions and spectroscopic энергетические структуры колебательные состояния инфракрасные спектры переходы
Online Access:	https://doi.org/10.1016/j.jqsrt.2021.107856
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=665357

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