A Cu-based MOF for the effective carboxylation of terminal alkynes with CO2 under mild conditions; Journal of CO2 Utilization; Vol. 39

A Cu-based MOF for the effective carboxylation of terminal alkynes with CO2 under mild conditions; Journal of CO2 Utilization; Vol. 39

Bibliographic Details
Parent link:Journal of CO2 Utilization
Vol. 39.— 2020.— [101177, 7 p.]
Corporate Author: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий (ИШХБМТ)
Other Authors: Shia Guangyong, Xu Wei, Wang Jichao, Yuan Ye, Chaemchuen Somboon, Verpoort F. V. K. Frensis Valter Kornelius
Summary:Title screen
The coordination of pyridylcarboxylate (isonicotinic acid, IN) with copper (II) fabricates a Cu(IN)-MOF. The characteristic properties of the Cu(IN)-MOF are obtained via different analysis techniques such as XRD, SEM, BET, ICP, TG, etc. The advantage of copper(II) coordinated with a bi-functional organic linker (IN), containing a pyridyl and carboxylate group, is demonstrated by the chemical properties of which the Cu(II)-based MOF exhibits excellent catalytic performance for the CO2 carboxylation of terminal alkynes. No noble-metal, co-catalyst, or additives are required to execute the reaction. The effectiveness of the Cu(IN)-MOF was demonstrated with a variety of substrates (>11). Moreover, the Cu(IN)-MOF, as a heterogeneous catalyst, can be recycled at least 5 times retaining its excellent catalytic performance. Herein, we report the first copper (II) metal-organic framework (Cu(IN)-MOF) applied for the carboxylation of alkynes with CO2 demonstrating several advantages such as stable catalyst, avoiding the use of an expensive noble-metal, straightforward synthesis.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2020
Subjects:
электронный ресурс
труды учёных ТПУ
MOF
carbon dioxide
carboxylation
alkynes
copper
углекислый газ
карбоксилирование
алкины
медь
Online Access:https://doi.org/10.1016/j.jcou.2020.101177
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=665249

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