A Cu-based MOF for the effective carboxylation of terminal alkynes with CO2 under mild conditions
| Parent link: | Journal of CO2 Utilization Vol. 39.— 2020.— [101177, 7 p.] |
|---|---|
| 企業作者: | |
| 其他作者: | , , , , , |
| 總結: | Title screen The coordination of pyridylcarboxylate (isonicotinic acid, IN) with copper (II) fabricates a Cu(IN)-MOF. The characteristic properties of the Cu(IN)-MOF are obtained via different analysis techniques such as XRD, SEM, BET, ICP, TG, etc. The advantage of copper(II) coordinated with a bi-functional organic linker (IN), containing a pyridyl and carboxylate group, is demonstrated by the chemical properties of which the Cu(II)-based MOF exhibits excellent catalytic performance for the CO2 carboxylation of terminal alkynes. No noble-metal, co-catalyst, or additives are required to execute the reaction. The effectiveness of the Cu(IN)-MOF was demonstrated with a variety of substrates (>11). Moreover, the Cu(IN)-MOF, as a heterogeneous catalyst, can be recycled at least 5 times retaining its excellent catalytic performance. Herein, we report the first copper (II) metal-organic framework (Cu(IN)-MOF) applied for the carboxylation of alkynes with CO2 demonstrating several advantages such as stable catalyst, avoiding the use of an expensive noble-metal, straightforward synthesis. Режим доступа: по договору с организацией-держателем ресурса |
| 語言: | 英语 |
| 出版: |
2020
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| 主題: | |
| 在線閱讀: | https://doi.org/10.1016/j.jcou.2020.101177 |
| 格式: | 電子 Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=665249 |
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| 200 | 1 | |a A Cu-based MOF for the effective carboxylation of terminal alkynes with CO2 under mild conditions |f Shia Guangyong, Xu Wei, Wang Jichao [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: 40 tit.] | ||
| 330 | |a The coordination of pyridylcarboxylate (isonicotinic acid, IN) with copper (II) fabricates a Cu(IN)-MOF. The characteristic properties of the Cu(IN)-MOF are obtained via different analysis techniques such as XRD, SEM, BET, ICP, TG, etc. The advantage of copper(II) coordinated with a bi-functional organic linker (IN), containing a pyridyl and carboxylate group, is demonstrated by the chemical properties of which the Cu(II)-based MOF exhibits excellent catalytic performance for the CO2 carboxylation of terminal alkynes. No noble-metal, co-catalyst, or additives are required to execute the reaction. The effectiveness of the Cu(IN)-MOF was demonstrated with a variety of substrates (>11). Moreover, the Cu(IN)-MOF, as a heterogeneous catalyst, can be recycled at least 5 times retaining its excellent catalytic performance. Herein, we report the first copper (II) metal-organic framework (Cu(IN)-MOF) applied for the carboxylation of alkynes with CO2 demonstrating several advantages such as stable catalyst, avoiding the use of an expensive noble-metal, straightforward synthesis. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Journal of CO2 Utilization | ||
| 463 | |t Vol. 39 |v [101177, 7 p.] |d 2020 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a MOF | |
| 610 | 1 | |a carbon dioxide | |
| 610 | 1 | |a carboxylation | |
| 610 | 1 | |a alkynes | |
| 610 | 1 | |a copper | |
| 610 | 1 | |a углекислый газ | |
| 610 | 1 | |a карбоксилирование | |
| 610 | 1 | |a алкины | |
| 610 | 1 | |a медь | |
| 701 | 0 | |a Shia Guangyong | |
| 701 | 0 | |a Xu Wei | |
| 701 | 0 | |a Wang Jichao | |
| 701 | 0 | |a Yuan Ye | |
| 701 | 0 | |a Chaemchuen Somboon |c chemist-technologist |c researcher at Tomsk Polytechnic University, Ph.D |f 1984- |3 (RuTPU)RU\TPU\pers\42620 | |
| 701 | 1 | |a Verpoort |b F. V. K. |c Chemical Engineer |c Professor of Tomsk Polytechnic University, doctor of chemical Sciences |f 1963- |g Frensis Valter Kornelius |3 (RuTPU)RU\TPU\pers\35059 |9 18334 | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Исследовательская школа химических и биомедицинских технологий (ИШХБМТ) |c (2017- ) |3 (RuTPU)RU\TPU\col\23537 |
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| 856 | 4 | |u https://doi.org/10.1016/j.jcou.2020.101177 | |
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